Scientific bibliography of Carl Djerassi

 

1946

1.         The Preparation and Partial Aromatization of 1, 4-Cho1estadienone-3 by the Dienone-Pheno1 Rearrangement.

J. A. C. S., 68, 1712 (1946).
by A. L. Wilds and C. Djerassi.

2.         The Dienone-Pheno1 Rearrangement Applied to Chrysene Derivatives. The Synthesis of 3-Hydroxy-1-methy1-chrysene and Related Compounds.

J. A. C. S., 68, 1715 (1946).
by A. L. Wilds and C. Djerassi.

3.         The Preparation of 5-Methoxybenzene-1,2,3-tri-carboxylic Acid.

J. A. C. S., 68, 1862 (1946).
by A. L. Wilds and C. Djerassi.

4.         The Synthesis of Estradiol and 1-Methy1estradio1 from Cholesterol.

J. A. C. S., 68, 2125 (1946).
by A. L. Wilds and C. Djerassi.

5.         Heterocyclic Amines with Antihistaminic Activity.

J. A. C. S., 68, 1999 (1946).

by C. P. Huttrer, C. Djerassi, W. L. Beears, R. L. Mayer and C. R. Scholz.

 

 

 1947

6.         The Ultraviolet Absorption Spectra of α,β-Un-saturated Ketones Conjugated with an Aromatic Nucleus.

J. A. C. S., 69, 1985 (1947).

by A. L. Wilds, L. W. Beck, W. J. Close, C. Djerassi, J. A. Johnson, Jr., T. L. Johnson and C. H. Shunk.

7.         Aryloxyacetamidines and 2-(Aryloxymethyl)-imidazolines.

J. A. C. S., 69, 1688 (1947).
by C. Djerassi and C. R. Scholz.

8.         The Bromination of Saturated 3-Ketosteroids with N-Bromo-Imides.

Experientia, 3, 107 (1947).

by C. Djerassi and C. R. Scholz.

9.         The Bromination of 3-Ketosteroids in Acetic Acid and the Effect of Trace Substances in the Solvent.

J. A. C. S., 69, 2404 (1947).
by C. Djerassi and C. R. Scholz.

10.       The Method of Molecular Rotation Differences Applied to 3-Ketosteroids of the Allo Series.

J. Org. Chem., 12, 823 (1947).
by C. Djerassi.

 

1948

11.       Brominations with Pyridine Hydrobromide Perbromide.

J. A. C. S., 70, 417 (1948).

by C. Djerassi and C. R. Scholz.

12.       The Preparation and Dienone-Pheno1 Rearrangement of 2-Bromo-1,4-androstadien-17-o1-3-one 17-Hexahydrobenzoate.

J. A. C. S., 70, 1911 (1948).
by C. Djerassi and C. R. Scholz.

13.       Identification of Crystalline Progesterone with 2,4-Dinitrophenylhydrazine.

Anal. Chem., 20, 880 (1948).
by C. Djerassi.

14.       5-Methy1doisyno1ic Acid and 1-Methy1estrone.

J. Org. Chem., 13, 697 (1948).
by C. Djerassi and C. R. Scholz.

15.       2-(Benzhydryloxymethy1) Imidazo1ine. A New Histamine Antagonist.

J. Org. Chem., 13, 830 (1948).
by C. Djerassi and C. R. Scholz.

16.       The Su1fonation of Some Polycyclic Ketones.

J. Org. Chem., 13, 848 (1948).
by C. Djerassi.

17.       Brominations with N-Bromosuccinimide and Related Compounds. The Wohl-Zieg1er Reaction.

Chem. Rev., 43, 271 (1948).
by C. Djerassi.

 

1949

 

18.       The Ultraviolet Absorption Spectra of Steroidal Dinitropheny1hydrazones.

J. A. C. S., 71, 1000 (1949).
by C. Djerassi and E. Ryan.

19.       The Scope and Mechanism of the Reaction of Dini-trophenylhydrazine with Steroidal Bromo Ketones.

J. A. C. S., 71, 1003 (1949).
by C. Djerassi.

20.       Δ1-Desoxycorticosterone Acetate.

Experientia, 5, 204 (1949).

by C. Djerassi, C. R. Scholz and J. H. Leathem.

21.       The Wohl-Zieg1er Bromination of Enol Acetates of 20-Keto Steroids.

J. Org. Chem., 14, 660 (1949).
by C. Djerassi and C. R. Scholz.

22.       The Preparation of Two Aromatic Analogs of Desoxycorticosterone Acetate.

J. A. C. S., 71, 3962 (1949).
by C. Djerassi and C. R. Scholz.

 

1950

23.       2-(Aryloxymethyl)Thiazolines and Penthiazolines.

J. Org. Chem., 15, 694 (1950).
by C. Djerassi and C. R. Scholz.

24.       2-Substituted-4-(2-Dialkylaminoethyl)Thiazoles.

J. Org. Chem., 15, 700 (1950).

by C. Dierassi, R. H. Mizzoni and C. R. Scholz.

25.       Preparation and Derivatives of N-Substituted Glycinonitriles.

J. A. C. S., 72, 3081 (1950).
by R. A. Turner and C. Djerassi.

26.       Steroids II. A Method for the Conversion of Allosteroids into Δ4-3-Ketosteroids.

J. A. C. S., 72, 1046 (1950).

by G. Rosenkranz, S. Kaufmann, J. Pataki and C. Djerassi.

27.       Steroids III. Bromination of Certain Keto-steroids and a Partial Synthesis of Estradiol, Estrone and Equilenin.

Nature, 165, 814 (1950).

G. Rosenkranz, C. Djerassi, S. Kaufmann, J. Pataki and J. Romo.

28.       Steroids IV. α-Iodoketones. A Method for the Conversion of Allosteroids into Δ4-3-Ketosteroids.

J. A. C. S., 72, 4077 (1950).

by G. Rosenkranz, O. Mancera, J. Gatica and C. Djerassi.

29.       Steroids V. The Synthesis of Adrenal Cortico-steroids and Analogs from Allopregnan-3β-ol-20-one.

J. A. C. S., 72, 4081 (1950).

by G. Rosenkranz, J. Pataki, S. Kaufmann, J. Berlin and C. Djerassi.

30.       Steroids VI. The Wohl-Ziegler Bromination of Steroidal 1,4-dien-3-ones. Partial Synthesis of Δ6-Dehydroestrone and Equilenin.

J. A. C. S., 72, 4531 (1950).

by S. Kaufmann; J. Pataki, G. Rosenkranz, J. Romo and C. Djerassi.

31.       Steroids VII. Contribution to the Bromination of Δ4-3-Ketosteroids and a New Partial Synthesis of the Natural Estrogens.

J. A. C. S., 72, 4534 (1950).

by C. Djerassi, G. Rosenkranz, J. Romo, S. Kaufmann and J. pataki.

32.       Steroids VIII. The Dienone-Phenol Rearrangement in the Steroid Series. Synthesis of a New Class of Estrogens.

J. A. C. S., 72, 4540 (1950).

by C. Djerassi, G. Rosenkranz, J. Romo, J. pataki and S. Kaufmann.

33.       Steroidal Sapogenins IV. Nomenclature of the Steroidal Sapogenins.

Nature, 166, 104 (1950).

by G. Rosenkranz and C. Djerassi.

34.       Steroids IX. The Dienone-Phenol Rearrangement in the Cholesterol Series.

J. Org. Chem., 15, 896 (1950).

by J. Romo, C. Djerassi and G. Rosenkranz.

35.       Steroids XI. l7-Ethynylandrostan-17β-ol and Androstane-2,17-dione.

J. A. C. S., 72, 5750 (1950).

by C. Djerassi, R. Yashin and G. Rosenkranz.

 

1951

 

36.       Steroids XV. The Bromination of 3-Ketosteroids of the Normal Series.

Experientia, 7, 93 (1951).

by C. Djerassi and G. Rosenkranz.

37.       Steroids XIV. Studies in the 3,6-Dihydroxypreg-nane Series.

J. Org. Chem., 16, 192 (1951).

by O. Mancera, G. Rosenkranz and C. Djerassi.

38.       Steroidal Sapogenins VI. Synthesis of Δ7-22-Isoallospirosten-3β-ol and Unsaturated Analogs.

J. Org. Chem., 16, 298 (1951).

by G. Rosenkranz, J. Romo, E. Batres and C. Djerassi.

39.       Steroidal Sapogenins VII. Experiments in the Hecogenin Series (part 1).

J. Org. Chem., 16, 303 (1951).

by C. Djerassi, H. Martinez and G. Rosenkranz.

40.       Steroids X. Aromatization Experiments in the Cholesterol Series.

J. Org. Chem., 15, 1289 (1951).

by J. Romo, G. Rosenkranz and C. Djerassi.

41.       Steroids XVII. A Steroidal Cyc1opropyl Ketone.

J. A. C. S., 73, 2383 (1951).

by A. Sandoval, G. Rosenkranz and C. Djerassi.

42.       Steroids XII. Aromatization Experiments in the Progesterone Series.

J. A. C. S., 73, 1523 (1951).

by C. Djerassi, G. Rosenkranz, J. Iriarte, J. Berlin and J. Romo.

43.       Steroids XIII. Reaction of α,β-Unsaturated Steroid Ketones with Benzylmercaptan. Thioeno1 Ether Formation and 1,4-Addition.

J. A. C. S., 73, 1528 (1951).

by J. Romo, M. Romero, C. Djerassi and G. Rosenkranz.

44.       The Dienone-Pheno1 Rearrangement.

J. A. C. S., 73, 990 (1951).

by A. Sandoval, L. Miramontes, G. Rosenkranz and C. Djerassi.

45.       Steroidal Sapogenins VIII. Steroids XVIII. Synthesis of Δ7,9(11)-A11opregnadien-3β-ol-20-one from Diosgenin and from Δ5-Pregnen-3β-ol-20-one.

J. Org. Chem., 16, 754 (1951).

by C. Djerassi, J. Romo and G. Rosenkranz.

46.       The Synthesis of 1-Ethyl-2,5-Dimethyl-8-Methoxyphenanthrene.

J. Org. Chem., 16, 899 (1951).

by J. Jerran, O. Mancera, G. Rosenkranz and C. Djerassi.

47.       The Effect of Bromine Substitution upon the Ul-traviolet Absorption Spectra of α,β-Unsaturated Ketones.

J. A. C. S., 73, 3263 (1951).

by A. L. Nussbaum, O. Mancera, R. Daniels, G. Rosenkranz and C. Djerassi.

48.       Steroids XXII. The Synthesis of 19-Norprogeste-rone.

J. A. C. S., 73, 3540 (1951).

by L. Miramontes, G. Rosenkranz and C. Djerassi.

49.       Steroids XXIV. Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids.

J. A. C. S., 73, 3546 (1951).

by G. Stork, J. Romo, G. Rosenkranz and C. Djerassi.

50.       Steroids XXV. Synthesis of Cortisone.

J. A. C. S., 73, 4055 (1951).

by G. Rosenkranz, J. Pataki and C. Djerassi.

51.       Steroids XXVI. Cortical Hormones from A11oste-roids: Synthesis of Cortisone from Reichstein's Compound D.

Nature, 168, 28 (1951).

by G. Rosenkranz, C. Djerassi, R. Yashin and J. Pataki. 

52.       Steroida1 Sapogenins IX. Oxidation of Δ5,16,20(22)-Furostatriene-3β,26-diol.

J. A. C. S., 73, 3820 (1951).

by A. Sandoval, J. Romo, G. Rosenkranz, S. Kaufmann and C. Djerassi.

53.       Steroidal Sapogenins XI. Experiments in the Hecogenin Series (part 2).

J. Org. Chem., 16, 1278 (1951).

by C. Djerassi, H. Martinez and G. Rosenkranz.

54.       Steroids XXVIII. Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (part 2).

J. A. C. S., 73, 4496 (1951).

by C. Djerassi, O. Mancera, G. Stork and G. Rosenkranz.

55.       Steroidal Sapogenins X. Unsaturated 22-Isospirosten-3-ones.

J. A. C. S., 73, 4654 (1951).

by R. Yashin, G. Rosenkranz and C. Djerassi.

56.       Steroids XX. Cyclic Steroidal Hemithioketa1s.

J. A. C. S., 73, 4961 (1951).

by J. Romo, G. Rosenkranz and C. Djerassi.

57.       Steroidal Sapogenins XII. The Configuration of the Hydroxyl Groups in Kammogenin, Yuccagenin, Li1agenin and Gitogenin.

J. A. C. S., ll., 5375 (1951).

58.       Steroids XXI. Δ7-Androstene-3β,17β-diol.

J. A. C. S., 73, 5478 (1951).

by F. Neumann, G. Rosenkranz, J. Romo and C. Djerassi.

59.       Steroids XXIII. Δ7,9(11)-Allopregnadiene-3β,20β-dio1 and Related Compounds.

J. A. C. S., 73, 5489 (1951).

by J. Romo, G. Rosenkranz and C. Djerassi.

60.       Steroidal Sapogenins XV. Experiments in the Hecogenin Series (part 3). Conversion to Cortisone.

J. A. C. S., 73, 5513 (1951).

by C. Djerassi, H. J. Ringold and G. Rosenkranz.

61.       Steroidal Sapogenins XIV. Δ4,6-22-Isospirostadien-3β-ol and Δ2,4,6-22-Isospirostatriene.

J. Org. Chem., 16, 1873 (1951).

by J. Romo, H. J. Ringold, G. Rosenkranz and C. Djerassi.

 

1952

62.       Steroidal Sapogenins XIII. Δ8(9)-22-Isospirosten-3α-ol.

J. A. C. S., 74, 422 (1952).

by C. Djerassi, R. Yashin and G. Rosenkranz.

63.       Steroids XXVII. Synthesis of A11opregnane-3β, 11β,17α,20β,21-Pento1 from Cortisone and Diosgenin.

J. Biol. Chem., 194, 115 (1952).

by C. Djerassi, G. Rosenkranz, J. Pataki and S. Kaufmann.

64.       Steroids XXIX. Synthesis of 11β-Hydroxyprogesterone.

J. Org. Chem., 17, 290 (1952).

by G. Rosenkranz, J. Pataki and C. Djerassi.

65.       Steroidal Sapogenins XVI. Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (part 3). 11-Oxygenated Sapogenins.

J. A. C. S., 74, 1712 (1952).

by C. Djerassi, E. Batres, M. Velasco and G. Rosenkranz.

66.       Steroidal Sapogenins XVII. 22-Isoallospirost-8(14)-en-3β-ol and 3β-Hydroxya11opregn-8(14)-en-20-one.

J. Chem. Soc., 1021 (1952).

by 0 Mancera, D. H. R. Barton, G. Rosenkranz and C. Djerassi.

67.       Steroidal Sapogenins XVIII. Experiments in the 5,6-Dihydrokryptogenin Series.

J. Org. Chem., 11, 426 (1952).

by A. L. Nussbaum, A. Sandoval, G. Rosenkranz and C. Djerassi.

68.       Steroids XXXI. Introduction of the 11-keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (part 4). Saturated 7, 11-Diones.

J. A. C. S., 74, 2918 (1952).

by J. Romo, G. Stork, G. Rosenkranz and C. Djerassi.

69.       Steroids XXXII. Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (part 5). Δ8-7-Ketones.

J. A. C. S., 74, 3321 (1952).

by C. Djerassi, O. Mancera, M. Velasco, G. Stork and G. Rosenkranz.

70.       Steroids XXXIII.  Δ7-Allopregnene-3β,17α-diol-20-one and Related Compounds.

J. A. C. S., 74, 3436 (1952).

by J. Pataki, G. Rosenkranz and C. Djerassi.

71.       Steroidal Sapogenins XIX. Sodium Borohydride Reduction of 3-Acetoxy-Δ3,5,7-22-Isospirostatriene and 3-Acetoxy-Δ3,5,7,9(11)-22-Isospirostatetraene.

J. A. C. S., 74, 3441 (1952).

by H. J. Ringold, G. Rosenkranz and C. Djerassi.

72.       Steroidal Sapogenins XX. Synthesis and Reactions of the Epimeric Δ5-22-Isospirosten-3β,7-diols.

J. A. C. S., 74, 3318 (1952).

by H. J. Ringold, G. Rosenkranz and C. Djerassi.

73.       Steroidal Sapogenins XXII. Steroids XXXIV. Degradation of 11-0xygenated Sapogenins. Synthesis of Allopregnane-3β,11β-diol-20-one and Allopregnane-3β,11α-diol-20-one.

J. A. C. S., 74, 3634 (1952).

by C. Djerassi, E. Batres, J. Romo and G. Rosenkranz.

74.       Steroids XXXIX. Synthesis of Δ4-Pregnene-11α,17α,21-triol-3,20-dione, the 11-epimer of Kendall's Compound F.

Chem. & Ind., 783 (1952).

by J. Romo, A. Zaffaroni, J. Hendrichs, G. Rosenkranz, C. Djerassi and F. Sondheimer.

75.       Steroidal Sapogenins XXI. Identification by the Absorption Spectra of their Sulfuric Acid Chromogens.

J. Org. Chem., 17, 747 (1952).

by G. Diaz, A. Zaffaroni, G. Rosenkranz and C. Djerassi.

76.       Steroidal Sapogenins XXIII. Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (part 6). New Approach to 11-Oxygenated Steroids.

J. A. C. S., 74, 2696 (1952).

by F. Sondheimer, R. Yashin, G. Rosenkranz and C. Djerassi.

77.       Steroids XXXV. Synthesis of llα-Hydroxyprogesterone.

J. Org. Chem., 17, 1066 (1952).

by O. Mancera, J. Romo, F. Sondheimer, G. Rosenkranz and C. Djerassi.

78.       Steroids XXXVII. A Ten Step Conversion of Progesterone to Cortisone.

J. A. C. S., 74, 3711 (1952).

by O. Mancera, A. Zaffaroni, B. A. Rubin, F. Sondheimer, G. Rosenkranz and C. Djerassi.

79.       Steroids XXXVIII. Synthesis of Allopregnane-3,11,20-trione-17α,21-diol (Dihydroallocortisone) from Allopregnan-3β-ol-11,20-dione.

J. A. C. S., 74, 5615 (1952).

by J. Pataki, G. Rosenkranz and C. Djerassi.

80.       Steroids XXX. Partial Synthesis of Allopregnane-3β,11β,21-triol-20-one and Allopregnane-3β,11β,17α,21-tetrol-20-one.

J. Biol. Chem., 195, 751 (1952).

by J. Pataki, G. Rosenkranz and C. Djerassi.

81.       Steroids XXXVI. Desu1furization Experiments in the 7-Ketopregnane Series.

J. Org. Chem., 17, 1413 (1952).

by J. Romo, G. Rosenkranz and C. Djerassi.

1953

82.       Steroidal Sapogenins XXV. Experiments in the Hecogenin Series (part 4). Degradation of 22α-5α-Spirostane-3β,12β-diol-11-one.

J. A. C. S., 75, 239 (1953).

by H. Martinez, H. J. Ringold, G. Rosenkranz and C. Djerassi.

83.       Steroidal Sapogenins XXIV. Synthesis and Side Chain Degradation of Δ7-22a-Spirosten-3β-ol.

J. Org. Chem., 18, 92 (1953).

by M. Velasco, J. Rivera, G. Rosenkranz, F. Sondheimer and C. Djerassi.

84.       Steroids XLI. Synthesis of 11α,17α-Dihydroxy-progesterone and of 11α,17α,21-Trihydroxyprogesterone, the 11-epimer of Kendall's Compound F.

J. A. C. S., 75, 1277 (1953).

by J. Romo, G. Rosenkranz, C. Djerassi and F. Sondheimer.

85.       Steroids XLII. Steroidal Sapogenins XXVI. The Chemical Reduction of Δ8-11-Keto and of Saturated 11-Keto Steroids. A New Approach to 11-Keto and 11α-Hydroxy Steroids.

J. A. C. S., 75, 1282 (1953).

by F. Sondheimer, O. Mancera, G. Rosenkranz and C. Djerassi.

86.       Steroids XLIII. A Ten Step Conversion of Progesterone to Cortisone. The Differential Reduction of Pregnane-3,20-diones with Sodium Borohydride.

J. A. C. S., 75, 1286 (1953).

by O. Mancera, H. J. Ringold, C. Djerassi, G. Rosenkranz and F. Sondheimer.

87.       The Dehydration of a Steroidal Δ8-11α-Hydroxy-7-Ketone.

J. A. C. S., 75, 1745 (1953).

by A. J. Lemin, G. Rosenkranz and C. Djerassi.

88.       Terpenoids I. The Triterpenes of the Cactus Lemaireocereus Thurberi.

J. A. C. S., 75, 2254 (1953).

by C. Djerassi, L. E. Geller and A. J. Lemin.

89.       Steroids XLIV. Synthesis of Δ4-Pregnene-11α,21-diol-3,20-dione Diacetate, the 11-Epimer of Corticosterone Acetate.

J. A. C. S., 75, 2601 (1953).

by F. Sondheimer, G. Rosenkranz, O. Mancera and C. Djerassi.

90.       Synthesis and Reactions of Chlorinated 3-Keto-steroids.

J. A. C. S., 75, 3500 (1953).

by J. J. Beereboom, C. Djerassi, D. Ginsburg and L. F. Fieser.

91.       α-Iodoketones (part 2). Reaction of Enol Acetates with N-Iodosuccinimide.

J. A. C. S., 75, 3493 (1953).
by C. Djerassi and C. T. Lenk.

92.       Steroidal Sapogenins XXVII. The Stereochemistry of the Catalytic Hydrogenation of Δ8-11-Keto Steroids.  Synthesis of 8-Iso and 14-Iso-11- Keto Sapogenins.

J. A. C. S., 75, 3496 (1953).

by C. Djerassi, W. Frick, G. Rosenkranz and F. Sondheimer.

93.       Steroids XLV. Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (part 8).  Performic Acid Oxidation of 7,9(11)-dienes.

J. A. C. S., 75, 3505 (1953).

by C. Djerassi, O. Mancera, J. Romo and G. Rosenkranz.

94.       Alkaloid Studies I.  The Isolation of Pilocereine from the Cactus Lophocereus schottii.

J. A. C. S., 75, 3632 (1953).

by C. Djerassi, N. Frick and L. E. Geller.

95.       Studies in Organic Sulfur Compounds V. Synthesis of 21-Thio1acetates of Adrenal Cortical Hormones.

J. A. C. S., 75, 3700 (1953).

by C. Djerassri and A. L. Nussbaum.

96.       Studies in Organic Sulfur Compounds VI. Cyclic Ethylene and Trimethylene Hemithioketals.

J. A. C. S., 75, 3704 (1953).
by C. Djerassri and M. Gorman.

97.       Steroidal Sapogenins XXVIII. The Reaction of Peracids with Enol Acetates of Δ8-7-Keto and Δ8-11-Keto Steroidal Sapogenins.

J. A. C. S., 75, 4428 (1953).

by O. Mancera, L. Miramontes, G. Rosenkranz, F. Sondheimer and C. Djerassi.

98.       Steroids XLVIII. 19-Norprogesterone, A Potent Progestational Hormone.

J. A. C. S., 75, 4440 (1953).

by C. Djerassi, L. Miramontes and G. Rosenkranz.

99.       Steroidal Sapogenins XXIX. Experiments in the Hecogenin Series (part 5). 22a-5β-Spirostan-3α-ol-12-one.

J. A. C. S., 75, 4885 (1953).

by C. Djerassi, A. J. Lemin, H. Martinez, G. Rosenkranz and F. Sondheimer.

100.     Oxidations with Ruthenium Tetroxide.

J. A. C. S., 75, 3838 (1953).
by C. Djerassi and R. R. Engle.

101.     Steroids XLIX. 19-Nor-Desoxycorticosterone, A Potent Mineralocorticoid Hormone.

J. A. C. S., 75, 4117 (1953).

by A. Sandoval, L. Miramontes, G. Rosenkranz, C. Djerassi and F. Sondheimer.

102.     Steroidal Sapogenins XXX. Synthesis and Side Chain Degradation of 22a-5β-Spirostan-3α-ol-11-one Acetate.

J. A. C. S., 75, 4430 (1953).

by G. Rosenkranz, M. Velasco, C. Djerassi and F. Sondheimer.

103.     Terpenoids II.  Experiments in the Cafestol Series.

J. Org. Chem., 18, 1449 (1953).

by C. Djerassi, E. Wilfred, L. Visco and A. J. Lemin.

 

104.     Terpenoids III. The Isolation of Erythrodiol, Oleanolic Acid and a New Triterpene Triol, Longispinogenin from the Cactus Lemaireocereus longispinus.

J. A. C. S., 75, 5940 (1953).

by C. Djerassi, R. M. McDonald and A. J. Lemin.

105.     Alkaloid Studies II.  Isolation of Reserpine and Narcotine from Rauwolfia Heterophylla.

J. A. C. S., 75, 5446 (1953).

by C. Djerassi, M. Gorman, A. L. Nussbaum and J. Reynoso.

106.     Synthesis of Cortisone and Related Steroids.

Vitamins and Hormones (Academic Press), 11, 205 (1953).
by C. Djerassi.

107.     Synthesis of 11-Oxygenated Steroids from Plant Sources.

Recent Progress in Hormone Research (Academic Press), 8, 1 (1953).

by G. Rosenkranz, F. Sondheimer, O. Mancera, J. Pataki, H. J. Ringold, J. Romo, C. Djerassi and G. Stork.

108.     Synthesis of 11-Oxygenated Steroids from Steroidal Sapogenins.

Ciba Foundation Colloquia on Endocrinology (Churchill, Ltd.), 7, 79-95 (1953).

by C. Djerassi and G. Rosenkranz.

 

1954

109.     Terpenoids IV. The Structures of the Cactus Triterpenes Gummosogenin and Longispinogenin.

Chem. & Ind., 161 (1954).

by C. Djerassi, L. E. Geller and A. J. Lemin.

110.     The Dienone-Phenol Rearrangement in the Benzo (c)-phenanthrene Series. A Case of Concurrent Methyl and Methylene Migration.

J. A. C. S., 76, 1741 (1954).

by C. Djerassi and T. T. Grossnickle.

111.     α-Iodoketones (part 3). Synthesis of 21-Iodo-Δ16-20-keto Steroids by the N-Iodosuccinimide-Enol Acetate Reaction.

J. A. C. S., 76, 1722 (1954).
by C. Djerassri and C. T. Lenk.

112.     Terpenoids V. The Isolation of Iresin, A New Sesquiterpene Lactone.

J. A. C. S., 76, 2966 (1954).

by C. Djerassi, P. Sengupta, J. Herran and F. Walls.

113.     Terpenoids VI. Dumortierigenin, A New Triterpene Lactone from the Cactus Lemaireocereus dumortieri.

J. A. C. S., 76, 2969 (1954).

by C. Djerassi, E. Farkas, A. J. Lemin, J. C. Collins and F. Walls.

114.     Terpenoids VII. Experiments in the Glycyrrhetic Acid Series.

J. A. C. S., 76, 4085 (1954).
by C. Djerassi and C. M. Foltz.

115.     Terpenoids VIII. The Structures of the Cactus Triterpenes Gummosogenin and Longispinogenin.

J. A. C. S., 76, 4089 (1954).

by C. Djerassi, L. E. Geller and A. J. Lemin.

116.     Steroids LIV. Synthesis of 19-Nor-17α-Ethynyltestosterone and 19-Nor-17α-Methyl-testosterone.

J. A. C. S., 76, 4092 (1954).

by C. Djerassi, L. Miramontes, G. Rosenkranz and F. Sondheimer.

 

117.     Steroidal Sapogenins XXXVII. Experiments in the Hecogenin Series (part 6). Conversion to Cortisone.

J. A. C. S., 76, 5533 (1954).

by C. Djerassi, H. J. Ringold and G. Rosenkranz.

118.     Steroidal Sapogenins XXXIV. Introduction of the 11-oxo- and the 11α-Hydroxy Group into Ring C Unsubstituted Steroids (part 9). The Epoxides of Δ7,9(11)-5α-Hydroxy Sapogenins.

J. Chem. Soc., 2346 (1954).

by C. Djerassi, A. J. Lemin, G. Rosenkranz and F. Sondheimer.

119.     Synthesis and Reactions of Mixed Bromo-chloro 3-Ketosteroids.

J. Org. Chem., 19, 1196 (1954).

by J. J. Beereboom and C. Djerassi.

120.     Lead Tetraacetate Oxidation of Steroidal Glycols. Some Observations on Quabagenin.

J. Org. Chem., 19, 1351 (1954).
by C. Dierassi and R. Ehrlich.

121.     Alkaloid Studies III.  Isolation of Pilocereine and Anhalonidine from Four Cactus Species.

J. A. C. S., 76, 3215 (1954).

by C. Djerassi, C. R. Smith, S. P. Marfey, R. N. McDonald, A. J. Lemin, S. K. Figdor and H. Estrada.

122.     Alkaloid Studies IV. The Isolation of Reserpine, Serpentine and Ajmaline from Rauwolfia Heterophylla.

J. A. C. S., 76, 4463 (1954).

by C. Djerassi, M. Gorman, A. L. Nussbaum and J. Reynoso.

123.     The Reaction of α-Halo Ketones with 2-Pyridinethiol.

J. A. C. S., 76, 4470 (1954).
by C. Djerassi and G. R. Pettit.

 

124.     The Constitution of Digitogenin.

Chem. & Ind., 728 (1954).

by C. Djerassi and T. T. Grossnickle.

125.     The Constitution and Stereochemistry of Samogenin, Markogenin and Mexogenin.

Chern. & Ind., 1320 (1954).

by C. Djerassi, J. Fishman, J. A. Moore.

126.     Steroids LV. Steroidal Sapogenins XXXV.  Chemical Introduction of the 6β-Hydroxy Group into Steroidal Δ4-3-Ketones by a Two Step Sequence.

J. Org. Chem., 19, 1509 (1954).

by J. Romo, G. Rosenkranz, C. Djerassi and F. Sondheimer.

127.     The Conversion of Diosgenin to Cortisone via 11-Ketosteroids of the 5β-Series.

J. A. C. S., 76, 5672 (1954).
by A. J. Lemin and C. Djerassi.

128.     Terpenoids XV. The Constitution of Iresin.  A New Fundamental Sesquiterpene Skeleton.

J. A. C. S., 76, 6410 (1954).

by C. Djerassi, W. Ritte1, A. L. Nussbaum, F. W. Donovan and J. Herran.

129.     Terpenoids IX. The Constitution of Machaeric Acid.

Chem. & Ind., 960 (1954).

by C. Djerassi and A. E. Lippman.

130.     Terpenoids X.  The Triterpenes of the Cactus Lemaireocereus hystrix.

J. A. C. S., 76, 5780 (1954).

by C. Djerassi and A. E. Lippman.

131.     The Stereochemical Course of the Reduction of a 14β-Δ8-11-0xo Steroid.

Chem. & Ind., 1228 (1954).

by C. Djerassi and G. H. Thomas.

132.     Steroids LXIII. Synthesis of Δ4-19-Norpregnene-11β,17β,21-triol-3,20-dione (19-Norhydrocortisone) and related 19-Noradrena1 Hormones.

J. A. C. S., 76, 6210 (1954).

by A. Zaffaroni, H. J. Ringold, G. Rosenkranz, F. Sondheimer, G. H. Thomas and C. Djerassi.

133.     Terpenoids XII.  The Constitution of the Cactus Triterpene Cochalic Acid.

Chem. & Ind., 1354 (1954).

by C. Djerassi and G. H. Thomas.

134.     Alkaloid Studies VI.  Cuauchichicine, A New Diterpenoid Alkaloid.

J. A. C. S., 76, 5889 (1954).

by C. Djerassi, C. R. Smith, S. K. Figdor, J. Herran and J. Romo.

 

 

1955

135.     Terpenoids XI. Investigation of Nine Cactus Species. Isolation of TWo New Triterpenes, Stellatogenin and Machaeric Acid.

J. A. C. S., 77, 1200 (1955).

by C. Djerassi, L. H. Liu, E. Farkas, A. E. Lippman, A. J. Lemin, L. E. Geller, R. N. McDonald and B. J. Taylor.

136.     Terpenoids XIII. The Structures of the Cactus Triterpenes Machaeric Acid and Machaerinic Acid.

J. A. C. S., 77, 1825 (1955).

by C. Djerassi and A. E. Lippman.

137.     Terpenoids XIV. The Stereochemistry of Sumaresinolic Acid and Its Conversion to Oleanolic Acid.

Helv. Chim. Acta, 38, 1304 (1955).
by C. Djerassi, G. H. Thomas and O. Jeger.

138.     Studies in Organic Sulfur Compounds VII. Lithium Aluminum Hydride Reduction of Xanthates to Mercaptans. Synthesis of Substituted β-Mercaptoethanols.

J. A. C. S., 77, 568 (1955).

by C. Djerassi, M. Gorman, F. X. Markley and E. B. Oldenburg.

139.     Steroids LXI. Synthesis of 19-Nor-desoxy-corticosterone, A Potent Mineralocorticoid Hormone.

J. A. C. S., 77, 148 (1955).

by A. Sandoval, G. H. Thomas, C. Djerassi, G. Rosenkranz and F. Sondheimer.

140.     Alkaloid Studies V. Synthesis of 1-Isopropyl and 1-Isobutyl-2-methyl-6,7-dimethoxy-l,2,3,4-tetrahydroisoquinoline.

J. A. C. S., 77, 484 (1955).

by C. Djerassi, J. J. Beereboom, S. P. Marfey and S. K. Figdor.

141.     The Stereochemistry of Digitogenin.

Chem. & Ind., 473 (1955).

by C. Djerassi, T. T. Grossnickle and L. B.

High.

142.     The Configuration of the Hydroxyl Groups in Gitogenin.

Chem. & Ind., 474 (1955).

by C. Djerassi, L. B. High, T. T. Gross-nickle, R. Ehrlich, J. A. Moore and R. B. Scott.

143.     Terpenoids XVI. The Constitution of the Cactus Triterpene Cocha1ic Acid.  Partial Reductions of Methyl Diketoechinocystate.

J. A. C. S., 77, 3579 (1955).

by C. Djerassi, G. H. Thomas and H. Monsimer.

 

144.     α-Iodoketones (part 4).  The Reaction of N-Iodosuccinimide with Enol Acetates of Δ4-3-Ketosteroids.

J. A. C. S., 77, 3826 (1955).

by C. Djerassi, J. Grossman and G. H. Thomas.

145.     Constitution and Stereochemistry of Samogenin, Markogenin and Mexogenin.

J. A. C. S., 77, 4291 (1955).
by C. Djerassi and J. Fishman.

146.     Optical Rotatory Dispersion Studies I. The Androstane Series.

J. A. C. S., 77, 4354 (1955).

by C. Djerassi, E. W. Foltz and A. E. Lippman.

147.     Optical Rotatory Dispersion Studies II. Steroid Hormones.

J. A. C. S., 77, 4359 (1955).

by E. W. Fo1tz, A. E. Lippman and C. Djerassi.

148.     Optical Rotatory Dispersion Studies III. The Cho1estane Series.

J. A. C. S., 77, 4364 (1955).

by A. E. Lippman, E. W. Foltz and C. Djerassi.

149.     Terpenoids XVII. The Cactus Triterpenes Thurberogenin and Stellatogenin.

J. A. C. S., 77, 5330 (1955).

by C. Djerassi, E. Farkas, L. H. Liu and G. H. Thomas.

150.     Studies in Organic Sulfur Compounds VIII. Introduction of Oxygen in the Raney Nickel Desulfurization of Hemithioketals (l,3-Oxathiolanes).

J. A. C. S., 77, 4647 (1955).

by C. Djerassi, M. Gorman and J. A. Henry.

151.     Alkaloid Studies VII. Tetraphyllin and Tetraphyllicine, Two New Alkaloids from Rauwolfia Tetraphylla.

Chem. & Ind., 627 (1955).

by C. Djerassi and J. Fishman.

152.     Correlation of Digitogenin with Progesterone.

J. A. C. S., 77, 3673 (1955).

by C. Djerassi, L. B. High, J. Fried and E. F. Sabo.

153.     Hydroxylation of Desoxycorticosterone with Neurospora crassa.

J. A. C. S., 77, 3926 (1955).

by D. Stone, M. Hayano, R. I. Dorfman, O. Hechter, C. H. Robinson and C. Djerassi.

154.     Terpenoids XIX. The Pentacyclic Skeleton of Cafestol.

J. Org. Chem., 20, 1046 (1955).

by C. Djerassi, H. Bendas and P. Sengupta.

 

 

 

155.     Alkaloid Studies VIII. The Structures of the Diterpenoid Alkaloids Laurifoline and Cuauchichicine.

J. A. C. S., 77, 4801 (1955).

by C. Djerassi, C. R. Smith, A. E. Lippman, S. K. Figdor and J. Herran.

l55a. The Structures of the Diterpenoid Alkaloids Laurifoline and Cuauchichicine.  Nomenclature Alteration.

J. A. C. S., 77, 6633 (1955).

by C. Djerassi, C. R. Smith, A. E. Lippman, S. K. Figdor and J. Herran.

156.     Terpenoids XVIII. Saponin from Ladino Clover (Trifolium repens).

J. A. C. S., 77, 4936 (1955).

by E. D. Walter, E. M. Bickoff, C. R. Thompson, C. H. Robinson and C. Djerassi.

157.     The Conversion of Androstane-3,17-dione to Androsterone.

J. A. C. S., 77, 4925 (1955).

by C. Djerassi, A. J. Manson and M. Gorman.

158.     Terpenoids XX. Constitution of Cafestol.

Chem. & Ind., 1481 (1955).
by H. Bendas and C. Djerassi.

159.     Terpenoids XXI. The Constitution of the Cactus Triterpene Queretaroic Acid.

Chem. & Ind., 1520 (1955).

by C. Djerassi, J. A. Henry, A. J. Lemin and T. Rios.

160.     Alkaloid Studies IX. Rauwolfia Alkaloids IV.  Isolation of Reserpine and other Alkaloids from Rauwolfia sellowii Muell. Argov.

J. A. C. S., 77, 6687 (1955).

by S. C. Pakrashi, C. Djerassi, R. Wasicky and N. Neuss.

 

1956

161.     Optical Rotatory Dispersion Studies  IV. Steroidal Sapogenins.

J. A. C. S., 78, 440 (1956).
by C. Djerassi and R. Ehrlich.

162.     Alkaloid Studies  X. Alkaloids of Two Brazilian Apocynaceae:  Rauwolfia Grandiflora Mart. and Lochnera (Vinca) Rosea (L.) Reichb. Var. Alba (Sweet) Hubbd.

Chem. & Ind., 173 (1956).

by W. B. Mors, P. Zaltzman, J. J. Beereboom, S. C. pakrashi and C. Djerassi.

163.     Alkaloid Studies XI. The Structures of Tetraphyllicine, Ajmalidine and Rauvomitine.

J. A. C. S., 78, 1259 (1956).

by C. Djerassi, M. Gorman, S. C. Pakrashi and R. B. Woodward.

 

164.     Methymycin. Reduction and Oxidation Studies.

J. A. C. S., 78, 1729 (1956).

by C. Djerassi; A. Bowers and H. N. Khastgir.

165.     The Partial Structure of Methymycin.

J. A. C. S., 78, 1733 (1956).

by C. Djerassi, A. Bowers, R. Hodges and B. Riniker.

166.     8-Isoprogesterone.

J. Org. Chem., 21, 490 (1956).

by C. Djerassi, A. J. Manson and A. Segaloff.

167.     Steroids LXXXI. Transformation of Sapogenins to Androgegs and Estrogens. Beckmann Rearrangement of Δl-20-Ketosteroids.

J. Org. Chem., 21, 520 (1956).

by G. Rosenkranz, O. Mancera, F. Sondheimer and C. Djerassi.

168.     Optical Rotatory Dispersion Studies  V. Effect of Isolated Carbonyl Groups and Double Bonds in the Cholestane Series.

J. A. C. S., 78, 3163 (1956).

by C. Djerassi, W. Closson and A. E. Lippman.

169.     Optical Rotatory Dispersion Studies  VI. The Bile Acid Series. Polycarbonyl Compounds and Stereochemical Differentiations.

J. A. C. S., 78, 3761 (1956).
by C. Djerassi and W. Closson.

170.     Optical Rotatory Dispersion Studies  VII. Application to Problems of Absolute Configurations.

J. A. C. S., 78, 6362 (1956).

by C. Djerassi, R. Riniker and B. Riniker.

171.     Alkaloid Studies  XII. Synthesis of Substituted 1-Isobutyl-2-methyl-1,2,3,4-tetrahydro-isoquinolines.

J. Org. Chem., 21, 975 (1956).

by C. Djerassi, F. X. Markley and R. Ehrlich.

172.     Alkaloid Studies XIII.  Isolation of Quebrachamine and of a New Dihydroindole Alkaloid, Spegazzinine, from Aspidosperma chakensis Spegazzini.

J. Org. Chem., 21, 979 (1956).

by O. O. Orazi, R. A. Corral, J. S. E. Holker and C. Djerassi.

173.     1-Methyl-19-norprogesterone and 1-Methyl-19-nor-17α-hydroxyprogesterone.

J. A. C. S., 78, 2479 (1956).

by C. Djerassi, A. E. Lippman and J. Grossman.

174.     An Unusual Cyclization in the Naphthalene Series.  Synthesis of 1-Ethylanthracene and of 4-Ethylphenanthrene.

J. A. C. S., 78, 2474 (1956).
by C. Djerassi and H. Bendas.

175.     The Constitution and Stereochemistry of Digitogenin.

J. A. C. S., 78, 3166 (1956).

by C. Djerassi, T. T. Grossnickle and L. B. High.

176.     The Structure of the Antibiotic Methymycin.

J. A. C. S., 78, 2907 (1956).
by C. Djerassi and J. A. Zderic. 

177.     Terpenoids XXII. Triterpenes from Some Mexican and South American Plants.

J. A. C. S., 78, 2312 (1956).

by C. Djerassi, A. Bowers, S. Burstein, H. Estrada, J. Grossman, J. Herran, A. J. Lemin, A. Manjarrez and S. C. Pakrashi.

178.     Terpenoids XXIII. Interconversion of Thurberogenin and Betu1inic Acid.

J. A. C. S., 78, 3534 (1956).
by C. Djerassi and R. Hodges.

179.     Terpenoids XXIV. The Structure of the Cactus Triterpene Queretaroic Acid.

J. A. C. S, 78, 3783 (1956).

by C. Djerassi, J. A. Henry, A. J. Lemin, T. Rios and G. H. Thomas.

180.     Terpenoids XXV. The Structure of the Cactus Triterpene Dumortierigenin.

J. A. C. S., 78, 5685 (1956).

by C. Djerassi, C. H. Robinson and D. B. Thomas.

181.     Alkaloid Studies XIV. The Structure of the Cactus Alkaloid Pi1ocereine.

J. A. C. S., 78, 3861 (1956).

by C. Djerassi, S. K. Figdor, J. M. Bobbitt and F. X. Markley.

182.     Optical Rotatory Dispersion Studies VIII. α,β-Unsaturated Ketones and Solvent Effects.

J. A. C. S., 78, 6377 (1956).

by C. Djerassi, R. Riniker and B. Riniker.

183.     Optical Rotatory Dispersion Studies IX. Intermediates in the Total Synthesis of Steroids.  Allotment of Absolute Configuration by Rotatory Dispersion Measurements.

Chem. & Ind., 988 (1956).
by C. Djerassi and W. K1yne.

184.     8-Isotestosterone.

J. Org. Chem., 21, 1056 (1956).

by C. Djerassi, H. Bendas and A. Sega1off.

185.     The Structure of the Antibiotic Methymycin.

J. A. C. S., 78, 6390 (1956).

by C. Djerassi and J. A. Zderic.

 

 

186.     The Direct Conversion of Steroidal Δ5-3β-Alcohols to Δ5- and Δ4-3-Ketones.

J. Org. Chern., 21, 1547 (1956).

by C. Djerassi, R. R. Engle and A. Bowers.

187.     Alkaloid Studies XV. Casimiroedine.

J. Org. Chem., 21, 1510 (1956).

by C. Djerassi, J. Herran, H. N. Khastgir, B. Riniker and J. Romo.

 

1957

188.     Alkaloid Studies XVI. Alkaloids of Rauwolfia tetraphylla L. The Structure of Tetraphylline and Tetraphyllicine.

J. A. C. S., 79, 1217 (1957).

by C. Djerassi, J. Fishman, M. Gorman, J. P. Kutney and C. Pakrashi.

189. Terpenoids XXVI.  Cactus Triterpenes.

Chapter in "Festschrift Arthur Stoll" (pp. 330 - 352) Birkhäuser, Basel, 1957.

by C. Djerassi.

190.     Alkaloid Studies XVII. The Structure of the Cactus Alkaloid Pilocereine.

J. A. C. S., 79, 2203 (1957).

by C. Djerassi, S. K. Figdor, J. M. Bobbitt and F. X. Markley.

191.     Optical Rotatory Dispersion Studies X. Determination of Absolute Configuration of α-Halo-cyclohexanones.

J. A. C. S., 79, 1506 (1957).
by C. Djerassi and W. Klyne.

192.     The Structure of the Antibiotic Neomethymycin.

J. A. C. S., 79, 2022 (1957).
by C. Djerassi and O. Halpern.

193.     Studies in Organic Sulfur Compounds IX. Preparation and Desulfurization of Optically Active 1,1-Diphenyl-3-mercaptopropan-2-ol.

J. A. C. S., 79, 2553 (1957).
by C. Djerassi and J. Grossman.

194.     The Synthesis of 8-Isoprogesterone and 8-Isotestosterone.

Tetrahedron, 1, 22 (1957).

by C. DjerassI, A. J. Manson and H. Bendas.

195.     Terpenoids XXVII. The Structure of the Cactus Triterpene Myrtillogenic Acid.

J. A. C. S., 79, 2901 (1957).

by C. Djerassi and H. G. Monsimer.

196.     Terpenoids XXVIII. The Triterpene Composition of the Genus Myrtillocactus.

J. A. C. S., 79, 3525 (1957).

by C. Djerassi, S. Burstein, H. Estrada, A. J. Lemin, A. E. Lippman, A. Manjarrez and H. G. Monsimer.

197.     Terpenoids XXIX. Iresin (part 2).  A New Fundamental Sesquiterpene Skeleton.

J. A. C. S., 79, 3528 (1957).
by C. Djerassi and W. Rittel.

198.     Steric Requirements in the Cyclization of Naphthalene Derivatives.

J. Org. Chem., 22, 393 (1957).
by C. Djerassi and G. R. Pettit.

199.     Optical Rotatory Dispersion Studies XI.  Structure et Dispersion Rotatoire.

Bull. Soc. Chim. France, 741 (1957).
by C. Djerassi.

200.     The Synthesis of Some 14-Iso-11-Ketosteroids. Stereochemical Course of Chemical and Catalytic Reduction of a 14β-Δ8-11-Ketosteroid.

J. A. C. S., 79, 3835 (1957).
by C. Djerassi and G. H. Thomas.

201.     Recording and Nomenclature of Optical Rotatory Dispersion.

Proc. Chem. Soc., 55 (1957). by C. Djerassi and W. Klyne.

202.     Macrolide Antibiotics VI. A Standard of Absolute Configuration Among Macrolide Antibiotics.

J. A. C. S., 79, 3926 (1957).
by C. Djerassi and O. Halpern.

203.     Optical Rotatory Dispersion Studies XII.  Absolute Configuration of Eperuic and Labdanolic Acids.

Tetrahedron, 1, 238 (1957).

by C. Djerassi and D. Marshall.

204.     Alkaloid Studies XVIII.  The Chemistry of Rosewood.  Isolation and Structure of Anibine and 4-Methoxyparacotoin.

J. A. C. S., 79, 4507 (1957).

by W. B. Mors, O. R. Gottlieb and C. Djerassi.

205.     Terpenoids XXX.  The Structure of the Cactus Triterpene Chichipegenin.

J. A. C. S., 79, 4468 (1957).

by A. Sandoval, A. Manjarrez, P. R. Leeming, G. H. Thomas and C. Dierassi.

206.     Terpenoids XXXI.  The Structure and Stereochemistry of Medicagenic Acid.

J. A. C. S., 79, 5292 (1957).

by C. Djerassi, D. B. Thomas, A. L. Livingston and C. R. Thompson.

207.     Optical Rotatory Dispersion Studies XIII. Assignment of Absolute Configuration to Certain Members of the Guaiano1ide Series of Sesquiterpenes.

J. Org. Chem., 22, 1361 (1957).

by C. Djerassi, J. Osiecki and W. Herz.

208.     Application of Optical Rotatory Dispersion Studies to Structural and Stereochemical Problems in Organic Chemistry.

Abstracts of the Fifteenth National Organic Chemistry Symposium, Rochester, June 1957, pp. 12 - 20.

by C. Djerassi.

209.     Alkaloid Studies XIX.  Alkaloids of Some Hawaiian Rauwolfia Species. The Structure of Sandwicine and its Interconversion with Ajmaline and Ajmalidine.

Tetrahedron, 1, 328 (1957).

by M. Gorman, N. Neuss, C. Djerassi, J. P. Kutney and P. J. Scheuer.

 

1958

210.     Terpenoids XXXII. The Structure of the Cactus Triterpene Treleasegenic Acid.  Ring Conformational Alterations in a Pentacyclic Triterpene.

J. A. C. S., 80, 1236 (1958).
by C. Djerassi and J. S. Mills.

211.     Optical Rotatory Dispersion Studies XIV. α-Haloketones (part 2).

J. A. C. S., 80, 1216 (1958).

by C. Djerassi, J. Osiecki, R. Riniker and B. Riniker.

212.     Alkaloid Studies XX.  Isolation and Structure of Two New Cactus Alkaloids, Piloceredine and Lophocerine.

Tetrahedron, 2, 58 (1958).

by C. Djerassi, T. Nakano and J. M. Bobbitt.

213.     The Structure of the Cactus Sterol Lophenol.  A Link in Sterol Biogenesis.

J. A. C. S., 80, 1005 (1958).

by C. Djerassi, J. S. Mills and R. Villotti.

214.     Recent Advances in the Chemistry of Steroid Transformation.

Abstract, First National Medicinal Chemistry Symposium, June 25, 1958, pp. l3a - l3i.
by C. Djerassi.

215.     Optical Rotatory Dispersion Studies XV.  Steroidal Ketols and Cardiac Aglycones.

Helv. Chim. Acta, 41, 250(1958).

by C. Djerassi, O. Halpern, V. Halpern, O. Schindler and C. Tamm.

216.     Terpenoids XXXIII.  The Structure and Probable Absolute Configuration of Cafestol.

J. A. C. S., 80, 247 (1958).

by C. Djerassi, M. Cais and L. A. Mitscher.

217.     On the Absolute Configuration of the Antibiotic Actidione.

J. A. C. S., 80, 1261 (1958).

by E. J. Eisenbraun, J. Osiecki and C. Djerassi.

 

218.     Über die Konfiguration des 19-nor-10,14β,17α-Progesterons.

Ann., 612, 93 (1958).

by C. Djerassi, M. Ehrenstein and G. W. Barber.

219.     Terpenoids XXXIV. Iresin (part 3).  Reactions of the Glycol System.

J. A. C. S., 80, 1972 (1958).

by C. Djerassi, F. W. Donovan, S. Burstein and R. Mauli.

220.     Steroids XCI.  Microbiological Oxidations of 19-Norprogesterone.

Tetrahedron, 2, 165 (1958).

by A. Bowers, C. Casas Campillo and C. Djerassi.

221.     Alkaloid Studies XXI.  Partial Structure of Casimiroedine.

Tetrahedron, 2, 167 (1958).

by C. Djerassi, C. Bankiewicz, A. L. Kapoor and B. Riniker.

222.     Steroids XCVI. The Synthesis of Equilin.

J. A. C. S., 80, 2596 (1958).

by J. A. Zderic, A. Bowers, H. Carpio and C. Djerassi.

223.     Terpenoids XXXV.  The Structure and Absolute Configuration of Iresin.

J. A. C. S., 80, 2593 (1958).
by C. Djerassi and S. Burstein.

224.     Naturally Occurring Oxygen Heterocyclics  II. Characterization of an Insecticidal Principle from Mammea americana L.

J. A. C. S., 80, 3686 (1958).

by C. Djerassi, E. J. Eisenbraun, B. Gilbert, A. J. Lemin, S. P. Marfey and M. P. Morris.

225.     Optical Rotatory Dispersion Studies  XVI. Synthesis and Conformation of Optically Active Octalones and Decalones.

J. A. C. S., 80, 3986 (1958).

by C. Djerassi and D. Marshall.

226.     Optical Rotatory Dispersion Studies XVII. Detection of Conformational Alterations.  Effects of Alkyl Groups and Double Bonds in Polycyclic System.

J. A. C. S., 80, 4001 (1958).

by C. Djerassi, O. Halpern, V. Halpern and B. Riniker.

227.     Optical Rotatory Dispersion Studies XVIII.  Demonstration of Conformational Mobility in 2-chloro-5-methylcyclohexanone.

Tetrahedron, 3, 319 (1958).

by C. Djerassi and L. E. Geller.

228.     Studies in Organic Sulfur Compounds  X. The Scope of the Raney Nickel Desulfurization of Cyclic Hemithioketals (1,3-0xathiolanes and 1,3-0xathianes).

J. A. C. S., 80, 4723 (1958).

by C. Djerassi, M. Shamma and T. Y. Kan.

229.     Macrolide Antibiotics  VII. The Structure of Neomethymycin.

Tetrahedron, 3, 255 (1958).

by C. Djerassi and O. Halpern.

230.     Naturally Occurring Oxygen Heterocyclics III. The Structure of the Isoflavone Tlatlancuayin.

J. A. C. S., 80, 5258 (1958).

by P. Crabbe’, P. R. Leeming and C. Djerassi.

231.     Optical Rotatory Dispersion Studies XIX.  8-Methylhydrindanones.

J. A. C. S., 80, 4853 (1958).

by C. Djerassi, D. Marshall and T. Nakano.

232.     Optical Rotatory Dispersion Studies XX. Transannular Nitrogen-Carbonyl Interaction in Cyclic Aminoketones and Optical Rotatory Dispersion.

J. A. C. S., 80, 4858 (1958).

by N. J. Leonard, J. A. Adamcik, C. Djerassi and O. Halpern.

233.     Steroids XCVII. Some Chemical and Biological Properties of 19-nor-17α-Ethynyltestosterone.

Ann. N. Y. Acad. Sci., 71, 500 (1958).
by D. A. McGinty and C. Djerassi. 

234.     Terpenoids XXXVI. Iresin (part 4). Isolation and Structure of Three Sesquiterpenes Related to Iresin.

Bull. Soc. Chim. Belg., 67, 632 (1958).

by P. Crabbe’, S. Burstein and C. Djerassi.

235.     Steroids XCVIII.  Synthesis of Some 10β-Hydroxy-10-norsteroids.

J. Org. Chem., 23, 1744 (1958).

by J. Perez Ruelas, J. Iriarte, F. Kincl and C. Djerassi.

236.     Steroids XCIX.  Synthesis of Ring B Oxygenated Estrogens.

J. A. C. S., 80, 6105 (1958).

by J. Iriarte, H. J. Ringold and C. Djerassi.

237.     Steroids C. Synthesis of 19-nor-Δ4-Pregnene-11β,17α,2l-triol-3,20-dione (19-norhydrocortisone) and Related 19-nor-Adrenal Hormones.

J. A. C. S., 80, 6110 (1958).

by A. Zaffaroni, H. J. Ringold, G. Rosenkranz, F. Sondheimer, G. H. Thomas and C. Djerassi.

238.     Research Trends in the Steroid Hormone Field.

Drug Trade News, March 1958.

by C. Djerassi and H. J. Ringold.

239.     Steroids CII. Synthesis of 19-norprogesterone from Estrone.

J. A. C. S., 80, 6118 (1958).

by J. S. Mills, H. J. Ringold and C. Djerassi.

 

240.     The Neutral Constituents of the Cactus Lophocereus schottii. The Structure of Lophenol (4α-methyl-Δ-cholesten-3β-ol). A Link in Sterol Biogenesis.

J. A. C. S., 80, 6284 (1958).

by C. Djerassi, G. W. Krakower, A. J. Lemin, L. H. Liu, J. S. Mills and R. Villoti.

241.     Macrolide Antibiotics VIII.  The Absolute Configuration of Certain Centers in Neomethymycin, Erythromycin and Related Antibiotics.

Tetrahedron, 4, 369 (1958).

by C. Djerassi, O. Halpern, D. I. Wilkinson and E. J. Eisenbraun.

242.     Steroids CVIII.  A New Class of Potent Cortical Hormones. 6α-Chlorocorticoids.

J. A. C. S., 80, 6464 (1958).

by H. J. Ringold, O. Mancera, C. Djerassi, A. Bowers, E. Batres, H. Martinez, E. Necoechea, J. Edwards, M. Velasco, C. Casas Campillo and R. I. Dorfman.

 

1959

243.     Optical Rotatory Dispersion Studies XXI. Effect of Ring Size.

J. A. C. S., 81, 237 (1959).

by C. Djerassi and G. W. Krakower.

244.     Steroids CVII. Δ5(6)-19-Nor-Steroids. A New Class of Potent Anabolic Agents.

J. A. C. S., 81, 436 (1959).

by J. Iriarte, C. Djerassi and H. J. Ringold.

245.     Steroidal Sapogenins XXXVIII. Synthesis of Cortisone from Botogenin.

J. A. C. S., 81, 439 (1959).
by O. Halpern and C. Djerassi.

246.     Reaction of the Steroidal Sapogenin Spiroketa1 System with Ethanedithio1.

J. Org. Chem., 24, 1 (1959).

by C. Djerassi, O. Halpern, G. R. Pettit and G. H. Thomas.

247.     Optical Rotatory Dispersion Studies XXII. Detection and Stereochemical Implication of Hemiketa1 Formation.

J. A. C. S., 81, 947 (1959).

by C. Djerassi, L. A. Mitscher and B. J. Mitscher.

248.     Naturally Occurring Oxygen Heterocyclics  IV. The Methylation of Pyronones.

J. A. C. S., 81, 2427 (1959).

by D. Herbst, W. B. Mors, O. R. Gottlieb and C. Djerassi.

249.     Naturally Occurring Oxygen Heterocyclics V. Mammein.

Tetrahedron Letters, 1, 10 (1959).

by C. Djerassi, E. J. Eisenbraun, R. A. Finnegan and B. Gilbert.

 

 

250.     Alkaloid Studies XXII. The Alkaloids of Vallesia Dichotoma Ruiz et Pav.

J. Org. Chem., 24, 314 (1959).

by J. S. E. Holker, M. Cais, F. A. Hochstein and C. Djerassi.

251.     Steroids CXII. Cycloethylene Ketal Formation of 19-Nor-Δ4-3-Keto Steroids.

J. A. C. S., 81, 3120 (1959).

by J. A. Zderic, D. Chavez Limon, H. J. Ringold and C. Djerassi.

252.     Steroids CXIII.  6-Methyl Estrogens.

J. Org. Chem., 24, 311 (1959).

by E. Velarde, J. Iriarte, H. J. Ringold and C. Djerassi.

253.     Steroids CXVI. 6α-Fluoro-l6α-Methylhydro-cortisone and Related Steroids.

Proc. Chem. Soc., 87 (1959).

by J. A. Edwards, A. Zaffaroni, H. J. Ringold and C. Djerassi.

254.     Steroids CXVII. 6α-Fluoro-l6α -Hydroxy Cortical Hormones.

J. A. C. S., 81, 1264 (1959).

by J. S. Mills, A. Bowers, C. Casas Campillo, C. Djerassi and H. J. Ringold.

255.     Terpenoids XXXVII. The Structure of the Pentacyclic Diterpene Cafestol. On the Absolute Configuration of Diterpenes and Alkaloids of the Phyllocladene Group.

J. A. C. S., 81, 2386 (1959).

by C. Djerassi, M. Cais and L. A. Mitscher.

256.     Optical Rotatory Dispersion Studies XXIII.  α-Haloketones (part 3).

J. A. C. S., 81, 2383 (1959).

by C. Djerassi, I. Fornaguera and O. Mancera.

257.     Research Trends in the Steroid Hormone Field

Drug Trade News, March 1959.

by C. Djerassi and H. J. Ringold.

258.     Optical Rotatory Dispersion Studies XXIV.  Effect of Distance of a Single Asymmetric Center from an Aliphatic Carbonyl Function.

J. A. C. S., 81, 2789 (1959).
by C. Djerassi and L. E. Geller.

259.     Terpenoids XL. Absolute Configuration of Eremophi1one.

J. A. C. S., 81, 2914 (1959).

by L. H. Zalkow, F. X. Markley and C. Djerassi.

260.     Steroids CXXII.  6α-Fluoro-16α-Methylcorticoids. Synthesis and Biological Activity.

J. A. C. S., 81, 3156 (1959).

by J. A. Edwards, H. J. Ringold and C. Djerassi. 

 

 

261.     Terpenoids XXXVIII. Interconversion of Eremophilone, Hydroxyeremophilone and Hydroxydihydroeremophilone. The Relative Stereochemistry of Eremophi1one and its Reduction Products.

J. A. C. S., 81, 3424 (1959).

by C. Djerassi, R. Mauli and L. H. Zalkow.

262.     Steroids CXVIII.  6-Methyl Derivatives of 17α-Hydroxyprogesterone and of Reichstein's Substance "S".

J. A. C. S., 81, 3712 (1959).

by H. J. Ringold, J. Perez Ruelas, E. Batres and C. Djerassi.

263.     Steroids CXIX. The Preparation of Some Vicinal Glycols in the Cortical Hormone Series.

J. Org. Chem., 24, 909 (1959).

by J. A. Zderic, H. Carpio and C. Djerassi.

264.     Optical Rotatory Dispersion Studies XXV.  Effect of Carbonyl Groups in Pentacyclic Triterpenes.

J. A. C. S., 81, 4587 (1959).

by C. Djerassi, J. Osiecki and W. Closson.

265.     Plant Steroids and Related Substances.

Fourth International Congress of Biochemistry (Vienna, 1958), Vol. IV, pp. 1 - 19, Pergamon Press, Ltd. (London, 1959).

by C. Djerassi.

266.     Optical Rotatory Dispersion Studies XXX. Demonstration of Boat Form in a 3-Keto Steroid.

J. A. C. S., 81, 4997 (1959).

by C. Djerassi, N. Finch and R. Mauli. 

267.     Optical Rotatory Dispersion Studies XXXI.
Anomalous Dispersion Curves of Dithiocarbamates of α-Amino Acids and Peptides. Stereochemical Correlations Between α-Hydroxy and α-Amino Acids.

J. A. C. S., 81, 5002 (1959).

by B. Sjöberg, A. Fredga and C. Djerassi.

268.     Optical Rotatory Dispersion Studies XXXII.
Some Recent Applications of Optical Rotatory Dispersion Studies to Organic Chemical Problems.

Rec. Chem. Prog., 20, 101 - 145 (1959).
by C. Djerassi. 

269.     Naturally Occurring Oxygen Heterocyclics VI. 4-Phenyl-5,7-dihydroxy-6-isovaleryl-8-isopen-tenylcoumarin.

Tetrahedron Letters, 13, 11 - 15 (1959).
by R. A. Finnegan and C. Djerassi.

 

 

270.     The Structure of Julocrotine.

Tetrahedron Letters, 14, 8 - 12 (1959).

by T. Nakano, C. Djerassi, R. A. Corral and O. O. Orazi.

271.     Steroids CXXIII.  19-Nor-6-methylandrostane Derivatives.

J. A. C. S., 81, 4566 (1959).

by R. Villotti, C. Djerassi and H. J. Ringold.

272.     Optical Rotatory Dispersion Studies XXVIII. The Absolute Configuration of the Sesquiter-penoid Petasin.

Helv. Chim. Acta, 42, 1785 (1959).
by A. Aebi and C. Djerassi.

273.     Optical Rotatory Dispersion Studies XXIX.
Absolute Configuration of Phytol.

Proc. Chem. Soc., 264 (1959).

by P. Crabbe’, C. Djerassi, E. J. Eisenbraun and S. Liu.

274.     Terpenoids XXXIX.  Iresin (part 5). Complete Structure and Absolute Configuration.

Tetrahedron, 7, 37 (1959).

by C. Djerassi and S. Burstein.

275.     The Constitutions of Dammarenolic and Nyctan-thic Acids.

Proc. Chem. Soc., 306 (1959).

by A. Arigoni, D. H. R. Barton, R. Bernas-coni, C. Djerassi, J. S. Mills and R. Wolff.

276.     Macrolide Antibiotics IX.  Filipin.

Proc. Chem. Soc., 316 (1959).

by B. Berkoz and C. Dierassi.

277.     The Absolute Configuration of Rosenonolactone and Related Diterpenoids.

J. A. C. S., 81, 5520 (1959).

by W. B. Whalley, B. Green, D. Arigoni, J. J. Britt and C. Djerassi.

 

1960

278.     Steroids CXXX. Synthesis of 12β-Hydroxypred-niso1one-11β,12β-Acetonide 21-Acetate.

J. A. C. S., 82, 446 (1960).

by J. A. Zderic, H. Carpio and C. Djerassi.

279.     Optical Rotatory Dispersion Studies XXVI.  α-Ha1oketones (part 4).

J. Org. Chem., 25, 1 (1960).

by C. Djerassi, L. E. Geller and E. J. Eisenbraun.

280.     Optical Rotatory Dispersion Studies XXVII.
Quantitative Studies of an α-Haloketone by the Rotatory Dispersion Method.

J. Org. Chem., 25, 6 (1960).

by N. L. Allinger, J. Allinger, L. E. Geller and C. Djerassi.

281.     Steroids CXXXIV. Derivatives of 17α-Ethynyl- testosterone and 17α-Ethynyl-19-nortestosterone.

J. A. C. S., 82, 1230 (1960).

by L. Knox, J. A. Zderic, J. Perez Ruelas, C. Djerassi and H. J. Ringold.

282.     Terpenoids XLI. The Constitutions of Dam-mareno1ic and Nyctanthic Acids.

J. Chem. Soc., 1900 (1960).

by D. Arigoni, D. H. R. Barton, R. Bernasconi, C. Djerassi, J. S. Mills and R. E. Wolff.

283.     Alkaloid Studies XXIII.  Isolation of 4 New Aspidosperma Alkaloids: Cy1indrocarpine, Refractine, Pyrifo1ine and Pyrifo1idine.

Experientia, 16, 61 (1960).

by B. Gilbert, L. D. Antonaccio, A. A. P. G. Archer and C. Djerassi.

284.     Optical Rotatory Dispersion Studies XXXIII.  α-Ha1oketones (part 6). Trans-2-bromo-5-t-buty1cyc1ohexanone.

J. Org. Chem., 25, 917 (1960).

by C. Djerassi, E. Warawa, R. E. Wolff and E. J. Eisenbraun.

285.     Steroids CXXXVI. Synthesis of a New Class of Potent Cortical Hormones. 6α-Fluoro-and 6α, 9α-Difluoro-16α-methylprednisolone and Related Steroids.

J. A. C. S., 82, 2318 (1960).

by J. A. Edwards, H. J. Ringold and C. Djerassi.

286.     Optical Rotatory Dispersion Studies XXXIV.  The Relative Stabilities of cis and trans Isomers (VIII). Kinetic and Equilibrium Measurements of Some Substituted Hydrindanones.

J. Org. Chem., 25, 922 (1960).

by N. L. Allinger, R. B. Hermann and C. Djerassi.

287.     Optical Rotatory Dispersion Studies XXXV.  On the Conformation of Substituted Cyclopen-tanones. Rotatory Dispersion and Spectral Data of Some Steroidal α-Halocyclopentanones.

Experientia, 16, 138 (1960).
by J. Fishman and C. Djerassi.

288. Steroids CXXXVII.  Synthesis of a New Class of Potent Cortical Hormones. 6α,9α-Difluoro-l6α-hydroxyprednisolone and its Acetonide.

J. A. C. S., 82, 3399 (1960).

by J. S. Mills, A. Bowers, C. Djerassi and H. J. Ringold.

289.     Steroids CXLIV. Synthesis of Some 6α,17α-Dihaloprogesterones.

J. Org. Chem., 25, 1056 (1960).

by J. S. Mills, O. Candiani and C. Djerassi.

290.     Terpenoids XLII. The Absolute Configuration of (-)-Methylisopulegone.

J. A. C. S., 32, 3476 (1960).

by E. J. Eisenbraun, F. Burian, Jeanne Osiecki and C. Djerassi.

 

291.     Terpenoids XLIII. On the Absolute Configuration of Guaiol. Correlation with Nepetalinic Acid.

J. A. C. S., 82, 3648 (1960).

by E. J. Eisenbraun, T. George, B. Riniker and C. Djerassi.

292.     Terpenoids XLIV. Synthetic Confirmation of the Structure and Absolute Configuration of Petasin.

J. A. C. S., 82, 4337 (1960).
by D. Herbst and C. Djerassi.

293.     Terpenoids XLV. Further Studies on the Structure and Absolute Configuration of Cafestol.

J. A. C. S., 82, 4342 (1960).

by R. A. Finnegan and C. Djerassi.

294.     Optical Rotatory Dispersion Studies XXXIX.  Configuration and Optical Rotatory Dispersion of Atropisomeric Biaryls.

J. A. C. S., 82, 4740 (1960).

by K. Mislow, M. A. W. Glass, R. E. O'Brien, P. Rutkin, D. H. Steinberg and C. Djerassi.

295.     Optical Rotatory Dispersion Studies XL.  The Absolute Configuration of Biaryls by Rotatory Dispersion Comparison with a Sesquiterpene.

J. A. C. S., 82, 5247 (1960).
by K. Mislow and C. Djerassi.

296.     Macrolide Antibiotics X.  The Biosynthesis of Methymycin.

Chem. & Ind., 1245 (1960).

by A. J. Birch, E. Pride, R. W. Rickards, P. J. Thompson, J. D. Dutcher, D. Perlman and C. Djerassi.

297.     Optical Rotatory Dispersion Studies XXXVI. α¬Haloketones (part 7). Demonstration of Boat Form in the Bromination of 2α-Methylcholestanone.

J. A. C. S., 82, 5488 (1960).

by C. Djerassi, N. Finch, R. C. Cookson and C. W. Bird.

298.     Steroids CXLV. 2-Methylandrostane Derivatives Demonstration of Boat Form in the Bromination of 2α-Methylandrostan-17β-ol-3-one.

J. A. C. S., 82, 5494 (1960).

by R. Mauli, H. J. Ringold and C. Djerassi. 

299.     Optical Rotatory Dispersion Studies XXXVII.  Steroids CXLVI. On the Mechanism and Stereo-chemical Course of the Bromination of 3-Keto Steroids and Their Enol Acetates.

J. A. C. S, 82, 5693 (1960).

by R. Villotti, H. J. Ringold and C. Djerassi.

300.     Optical Rotatory Dispersion Studies XLIII.  Absolute Configurational Assignment of α-Substituted Carboxylic Acids by Anomalous Rotatory Dispersion of Their Acylthiourea Deriva-times.

J. A. C. S., 82, 5755 (1960).
by C. Djerassi and K. Undheim.

301.     Bromination of 2-0xo-Steroids.

Chem. & Ind., 1385 (1960).
by C. Djerassi and T. Nakano.

302.     Optical Rotatory Dispersion Studies XLIV.  Anomalous Rotatory Dispersion Curves of Olefin Derivatives. Osmate Esters.

J. A. C. S., 82, 5953 (1960).

by E. Bunnenberg and C. Djerassi.

303.     Alkaloid Studies XXV.  The Structures of the Aspidosperma Alkaloids Cylindrocarpine and Cylindrocarpidine.

Experientia, 16, 532 (1960).

by C. Djerassi, A. A. P. G. Archer, T. George, B. Gilbert, J. N. Shoolery and L. F. Johnson.

304.     Terpenoids XLVIII. The Absolute Configuration of Eremophilone and Related Sesquiterpenes.

J. A. C. S., 82, 6354 (1960).

by L. H. Zalkow, F. X. Markley and C. Djerassi.

305.     Naturally Occurring Oxygen Heterocyclics VII.
The Structure of Mammein.

J. Org. Chem., 25, 2164 (1960).

by C. Djerassi, E. J. Eisenbraun, R. A. Finnegan and B. Gilbert.

306.     Naturally Occurring Oxygen Heterocyclics VIII.
Synthesis of Some Coumarins Related to Mammein.

J. Org. Chem., 25, 2169 (1960).

by R. A. Finnegan, B. Gilbert, E. J. Eisen¬braun and C. Djerassi.

307.     Naturally Occurring Oxygen Heterocyclics IX.
Isolation and Characterization of Genipin.

J. Org. Chem., 25, 2174 (1960).

by C. Djerassi, J. D. Gray and Fred A. Kincl.

 

1961

308.     Chiapagenin and Isochiapagenin. Two New Steroidal Sapogenins from Dioscorea Chiapasensis.

J. Org. Chem., 26, 155 (1961).

by I. T. Harrison, M. Velasco and C. Djerassi.

309.     Terpenoids XLVI.  Copalic Acid.

J. Org. Chem., 26, 167 (1961).
by T. Nakano and C. Djerassi.

310.     Optical Rotatory Dispersion Studies XLI.  α-Haloketones (part 9). Bromination of Optically Active cis-l-Decalone.  Demonstration of Conformational Mobility by Rotatory Dispersion.

J. A. C. S., 83, 736 (1961).

by C. Djerassi and J. Staunton.

311.     Alkaloid Studies XXVII. The Structure of Skytanthine.

Chem. & Ind., 210 (1961).

by C. Djerassi, J. P. Kutney, M. Shamma, J. N. Shoolery and L. F. Johnson.

312.     Optical Rotatory Dispersion Studies XLV.
Demonstration of Conformational Mobility in an α-Hydroxycyclohexanone.

Chem. & Ind., 258 (1961).

by C. Djerassi, R. Records and B. Bach.

313.     Alkaloid Studies XXIX. On the Absolute Configuration of the Diterpene Alkaloids Related to Veatchine and Atisine.

Tetrahedron Letters, 119 (1961).
by H. Vorbrueggen and C. Djerassi.

314.     Steroids CLVI.  Ring D Unsaturated l6-Methylated Corticosteroids.

J. Org. Chern., 26, 871 (1961).

by E. Batres, T. Cardenas, J. A. Edwards, G. Monroy, O. Mancera, C. Djerassi and H. J. Ringold.

315.     Optical Rotatory Dispersion Studies LII.  Determination of the Absolute Configuration of Jatamansone (Valeranone) by the Axial α-Haloketone Rule.

Tetrahedron Letters, 237 (1961).

by C. Djerassi, T. R. Govindachari, B. R. Pai and K. K. Purushothaman. 

316.     Naturally Occurring Oxygen Heterocyclics X. 4-Phenyl-5,7-Dihydroxy-6-Isova1eryl-8-Isopentenylcourmarin.

J. Org. Chem., 26, 1180 (1961).

by R. A. Finnegan, M. P. Morris and C. Djerassi.

317.     Alkaloid Studies XXIV.  Structure of Julo-crotine.

J. Org. Chem., 26, 1184 (1961).

by T. Nakano, C. Djerassi, R. A. Corral and O. O. Orazi.

318.     Terpenoids XLVII. The Structure of Genipin.

J. Org. Chern., 26, 1192 (1961).

by C. Djerassi, T. Nakano, A. N. James, L. H. Za1kow, E. J. Eisenbraun and J. N. Shoo1ery.

319.     Alkaloid Studies XXVIII.  Structure of the Alkaloid Arborinine.

Chem. & Ind., 464 (1961).

by S. C. Pakrashi, S. K. Roy, L. F. Johnson, T. George and C. Djerassi.

320.     Alkaloid Studies XXVI. The Constitution of PYrifo1idine.

Experientia, 17, 162 (1961).

by C. Djerassi, B. Gilbert, J. N. Shoo1ery, L. F. Johnson and K. Biernann.

 

321.     Optical Rotatory Dispersion Studies XXXVIII.
The Relative Stereochemistry of the Rotenoids.

J. Chem. Soc., 1448 (1961).

by C. Djerassi, W. D. Ollis and R. C. Russell.

322.     Optical Rotatory Dispersion Studies XLVIII.
The Nitroso Chrornophore.

J. A. C. S., 83, 2307 (1961).

by C. Djerassi, E. Lund, E. Bunnenberg and B. Sjöberg.

323.     Steroids and Terpenoids from Different Iresin Species.

Bull. Soc. Chim. Be1g., 70, 168 (1961).

by P. Crabbe’, E. A. Azpeitia and C. Djerassi.

324.     Optical Rotatory Dispersion Studies XLII.  Disulfides and Diselenides.

Acta Chem. Scand., 15, 417 (1961).

by C. Djerassi, A. Fredga and B. Sjöberg.

325.     Steroidal Sapogenins XL. Reaction of 12-oxo-sapogenins with Selenium Dioxide: Synthesis of 3β~-Hydroxypregna-5,9(11),16-triene-20-one from Botogenin.

J. Chem. Soc., 1859 (1961).

by A. Bowers, E. Denot, M. B. Sanchez, F. Neumann and C. Djerassi.

326.     Optical Rotatory Dispersion Studies LIV.
Optical Rotatory Dispersion.

Endeavour, 20, 138 (1961).
by C. Djerassi.

327.     Optical Rotatory Dispersion Studies LIII. A Generalization of the Octant Rule.

J. A. C. S., 83, 2771 (1961).

by K. Mislow, M. A. W. Glass, A. Moscowitz and C. Djerassi.

328.     Optical Rotatory Dispersion Studies XLVII.
Application of Anomalous Optical Rotatory Dispersion to Organic Chemical Problems.

Tetrahedron, 13, 13 (1961).
by C. Djerassi.

329.     Alkaloid Studies XXXI. A Direct Correlation of the Diterpene Alkaloids and Hydrocarbons of the Phyllocladene Group. Interconversion of Garryfoline and Steviol.

J. A. C. S., 83, 3163 (1961).

by E. Mosettig; P. Quitt, U. Beg1inger, J. A. Waters, H. Vorbrueggen and C. Djerassi.

330.     Optical Rotatory Dispersion Studies LV.  Application of Optical Rotatory Dispersion Studies to Problems in Natural Products Chemistry.

Pure and App1. Chem., 2, 475 (1961).

by C. Djerassi.

331.     Optical Rotatory Dispersion Studies LVII.  The Octant Rule and the t-Butyl Group.  Evidence for a Twist Form in cis-t-Butyl-5-methylcyclo- hexanone.

J. A. C. S., 83, 3334 (1961).

by C. Djerassi; E. J. Warawa, J. M. Berdahl and E. J. Eisenbraun.

332.     Optical Rotatory Dispersion Studies LX.  Optical Rotatory Dispersion.

Science, 134, 649 (1961).
by C. Djerassi.

333.     Terpenoids L. Cycloart-23-ene-3β,25-diol: A New Cyclopropane-containing Triterpene from Spanish Moss.

Chem. & Ind., 1311 (1961).

by R. McCrindle and C. Djerassi.

334.     Optical Rotatory Dispersion Studies LVIII.
The Complete Absolute Configuration of Steviol, Kaurene and the Diterpene Alkaloids of the Garryfoline and Atisine Groups.

J. A. C. S., 83, 3720 (1961).

by C. Djerassi, P. Quitt, E. Mosettig, R. C. Cambie, P. S. Rutledge and L. H. Briggs.

335.     Optical Rotatory Dispersion Studies XLIX.  Anomalous Rotatory Dispersion of Optically Active Terpene Trithiones.

Chem. Ber., 94, 2305 (1961).

by C. Djerassi and A. Lüttringhaus.

336.     Optical Rotatory Dispersion Studies L.  The Conformers of trans-2-Chloro-5-methylcyclo-hexanone.

J. Org. Chem., 26, 3521 (1961).

by J. Allinger, N. L. Allinger, L. E. Geller and C. Djerassi.

337.     Macrolide Antibiotics XI.  The Structure of the Macrolide Antibiotic Filipin.

Tetrahedron Letters, 383 (1961).

by C. Djerassi, M. Ishikawa, H. Budzikiewicz, J. N. Shoolery and L. F. Johnson.

338.     Optical Rotatory Dispersion Studies XLVI.
Stereochemical Assignments through Anomalous Rotatory Dispersion Curves of α-Aminoacid Derivatives. 3-Phenyl-2-thiohydantoins and α-thionocarbethoxy Amino Acids.

Acta Chem. Scand., 15, 903 (1961).

by C. Djerassi, K. Undheim, R. C. Sheppard, W. G. Terry and B. Sjöberg.

339.     Structure and the Optical Rotatory Dispersion of Saturated Ketones.

J. A. C. S., 83, 4013 (1961).

by W. Moffitt, R. B. Woodward, A. Moscowitz, W. Klyne and C. Djerassi.

340.     Terpenoids XLIX.  Preparation of Optically Active Polyalkylcyclohexanones from (+)-Pu1egone, (-)-Menthone and (-)-Carvone.

J. A. C. S., 83, 4433 (1961).

by C. Djerassi; J. Osiecki and E. J. Eisenbraun.

341.     Optical Rotatory Dispersion Studies LIX.  The Octant Rule and Deuterium. Synthesis of 3-Deuteriocyclopentanone.

J. A. C. S., 83, 4609 (1961).
by C. Djerassi and B. Tursch.

342.     Optical Rotatory Dispersion Studies LI.  Absolute Configurational Assignments of α-Amino Acids and Peptides through Anomalous Rotatory Dispersion of N-phtha1oyl Derivatives.

J. Org. Chem., 26, 4509 (1961).

by C. Djerassi, E. Lund, E. Bunnenberg and J. C. Sheehan.

343.     Optical Rotatory Dispersion Studies LVI.  Thiones.

J. Org. Chem., 26, 4675 (1961).
by C. Djerassi and D. Herbst.

344.     Optical Rotatory Dispersion Studies LXI.  Optical Rotatory Dispersion and Spectral Data of Some Steroidal Ring D Ketol Acetates of the 14β Series.

Experientia, 17, 565 (1961).

by C. Djerassi, J. Fishman and T. Nambara.

345.     The Structure of the Cactus Sterol Peniocerol.

Proc. Chem. Soc., 450 (1961).

by C. Djerassi, R. D. H. Murray and R. Villotti.

346.     Alkaloid Studies XXX.  Isolation and Constitution of Three New Aspidosperma Alkaloids: Cylindrocarpine, Cylindrocarpidine and Pyrifolidine.

Tetrahedron, 16, 212 (1961).

by C. Djerassi, A. A. P. G. Archer, T. George, B. Gilbert and L. D. Antonaccio.

347.     Optical Rotatory Dispersion Studies. LXII. Configurational Assignments Among the Aporphine Alkaloids.

Experientia, 18, 53 (1962)

by C. Djerassi, K. Mislow and M. Shamma.

348.     Optical Rotatory Dispersion Studies. LXIII. Halogen Atoms and the Octant Rule.

Chem. Ind., 177 (1962)
by C. S. Barnes and C. Djerassi.

349.     Steroids. CLXXVII. New Approaches to C-11 Oxygenated 19-Norpregnones.

J. Org. Chem., 27, 361 (1962)

by A. Bowers, J. S. Mills, C. Casas­Campillo and C. Djerassi.

350.     Alkaloid Studies. XXXII. Studies on Skytanthus Acutus. The Structure of the Monoterpenoid Alkaloid Skytanthine.

Tetrahedron, 18, 183 (1962)

by C. Djerassi, J. P. Kutney and M. Shamma.

351.     Mass Spectrometry in Structural and Stereochemical Problems. IV. Vindolinine.

Proc. Natl. Acad. Sci. U.S., 48, 113 (1962)

by C. Djerassi, S. E. Flores, H. Budzikiewicz,

J. M. Wilson, L. J. Durham, J. LeMen,

M.-M. Janot, M. Plat, M. Gorman and N. Neuss.

352.     Optical Rotatory Dispersion. LXIX. The Absolute Configuration of the 2-Methylcyclohexanols and Some Observations on a Twist Form in the Conformational Equilibrium of 2-Methylcyclohexanone.

J.A.C.S., 84, 874 (1962)

by C. Beard, C. Djerassi, T. Elliott and R. C. C. Tao.

353.     Optical Rotatory Dispersion Studies.  LXXII. Inherently Dissymmetric Chromophores. Optical Rotatory Dispersion of α,β-unsaturated Ketones and Conformational Analysis of Cyclohexenones.

J.A.C.S., 84, 870 (1962)

by C. Djerassi, R. Records, E. Bunnenberg,

K. Mislow and A. Moscowitz.

354.     Studies in Organic Sulfur Compounds. XI.  On the Reaction of Enamines with Hydrogen Sulfide.

J. Org. Chem., 27, 1041 (1962)

by C. Djerassi and B. Tursch.

355.     Studies in Organic Sulfur Compounds. XII.
Preparation of Inaccessible Enamine Amides by Desulfurization of Thiazolidines and Thiazolidinones.

J. Org. Chem., 27, 1112 (1962)

by C. Djerassi, N. Crossley and M. A. Kielczewski.

356.     Mass Spectrometry in Structural and Stereochemical Problems. II. Pyrifoline and Refractidine.

Tetrahedron Letters, 59 (1962)
by B. Gilbert, J. M. Ferreira, R. J. Oweller,

C. E. Swanholm, H. Budzikiewicz, L. J. Durham and C. Djerassi.

357.     Mass Spectrometry in Structural and Stereochemical Problems. III. Spegazzinine and Spegazzinidine.

Experientia, 18, 113 (1962)
by C. Djerassi, H. W. Brewer, H. Budzikiewicz, O. O. Orazi and R. A. Corral.

358.     Optical Rotatory Dispersion Studies. LXIV. Detection of Conformational Changes Caused by Equatorial Methyl Groups.

J.A.C.S., 84, 1249 (1962)

by C. Djerassi, E. Lund and A. A. Akhrem.

359.     Steroids. CXCI. Some Reactions of a 6-Methyl-Δ5-3β- Hydroxy Steroid System.

J. Org. Chem., 27, 1139 (1962)

by J. Iriarte, J. N. Shoolery and C. Djerassi.

360.     Optical Rotatory Dispersion Studies. LXV. Differentiation of Epimeric Steroidal Alcohols by Anomalous Rotatory Dispersion. Some Observations on the Nitrite Chromophore.

J. Org. Chem., 27, 1173 (1962)

by C. Djerassi, I. T. Harrison, O. Zagneetko and A. L. Nussbaum.

361.     Optical Rotatory Dispersion Studies. LXVIII. Configuration, Conformation and Rotatory Dispersion of Optically Active Biaryls.

J.A.C.S., 84, 1455 (1962)

by K. Mislow, M. A. W. Glass, R. E. O'Brien, P. Rutkin, D. M. Steinberg, J. Weiss and C. Djerassi.

362.     Mass Spectrometry in Structural and Stereochemical Problems. I. Steroid Ketones.

J.A.C.S., 84, 1430 (1962)
by H. Budzikiewicz and C. Djerassi.

363.     Mass Spectrometry in Structural and Stereochemical Problems. V. Refractine and Aspidefractine.

J.A.C.S., 84, 1499 (1962)
by C. Djerassi, T. George, N. Finch, H. F. Lodish, H. Budzikiewicz and B. Gilbert.

364.     Steroids. CLXXII. Factors Controlling the Direction of Enol Acetylation of 3-Oxo-steroids.

J. Chem. Sac., 1323 (1962)
by B. Berkoz, E. P. Chavez and C. Djerassi.

365.     Naturally Occurring Oxygen Heterocyclics. XI. Veraguensin.

J. Chem. Soc., 1459 (1962)
by N. S. Crossley and C. Djerassi.

366.     Recent Applications of Optical Rotatory Dispersion to Organic Chemistry.

Chemistry (Taiwan), No. 4, 249-254 (1961)
by C. Djerassi.

367.     Mass Spectrometry in Structural and Stereochemical Problems. VII. Vincadifformine (Alcaloides des Pervenches).

Tetrahedron Letters, 235 (1962)
by C. Djerassi, H. Budzikiewicz, J. M. Wilson, J. Gosset, J. LeMen and M.-M. Janot.

368.     Optical Rotatory Dispersion Studies. LXVI.
Optical Rotatory Dispersion Associated with Dissymmetric Non-Conjugated Chromophores. An Extension of the Octant Rule.

J.A.C.S., 84, 1945 (1962)
by A. Moscowitz, K. Mislow, M. A. W. Glass and C. Djerassi.

369.     Optical Rotatory Dispersion Studies. LXXI. Halogen Atoms and the Octant Rule. The Conformations of Some 5α–Halocholestan-3–ones.

J.A.C.S., 84, 1962 (1962)
by C. S. Barnes and C. Djerassi.

370.     Mass Spectrometry in Structural and Stereochemical Problems. VIII. Unsaturated Pectacyclic Triterpenoids.

Tetrahedron Letters, 263 (1962)
by C. Djerassi, H. Budzikiewicz and J. M. Wilson.

371.     Mass Spectrometry in Structural and Stereochemical Problems. IX. Tabersonine.

Tetrahedron Letters. 271 (1962)
by M. Plat, J. LeMen, M.–M. Janot, J. M. Wilson, H. Budzikiewicz, L. J. Durham, Y. Nakagawa, and C. Djerassi.

372.     A New Route to 1–Oxygenated Steroids.

J. Org. Chem., 27, 2205 (1962)
by C. Djerassi, D. H. Williams and B. Berkoz.

373.     Alkaloid Studies. XXXIII. Mass Spectrometry in Structural and Stereochemical Problems. VI. Polyneuridine, A New Alkaloid from Aspidosperma Polynauron and Some Observations on Mass Spectra of Indole Alkaloids.

J.A.C.S., 84, 2161 (1962)
by L. D. Antonaccio, N. A. Pereira, B. Gilbert, H. Vorbrueggen, H. Budzikiewicz, J. M. Wilson, L. J. Durham and C. Djerassi.

374.     Optical Rotatory Dispersion Studies. LXXV. Optical Rotatory Dispersion and the Twist Conformation of Cyclohexanones.

Proc. Natl. Acad. Sci. U.S., 48, 1093 (1962)
by C. Djerassi and W. Klyne.

375.     Alkaloid Studies. XXIIV. Structure of the Alkaloid Casimiroedine.

Tetrahedron Letters, 357 (1962)
by S. Raman, J. Reddy, W. N. Lipscomb, A. L. Kapoor and C. Djerassi.

376.     Optical Rotatory Dispersion Studies. LXVII.
Stereochemistry of the Isomeric Isopulegones. Preparation of (+)–Isopulegone by Thermal Isomerization of (+)–Pulegone.

Ber., 95, 1400 (1962)

by G. Ohloff, J. Osiecki and C. Djerassi.

377.     Mass Spectrometry in Structural and Stereochemical Problems. X. Structure of Mossambine.

Bull. Soc. Chim. France, 1088 (1962)
by X. Monseur, R. Goutarel, J. LeMen, J. M. Wilson, H. Budzikiewicz and C. Djerassi.

378.     Mass Spectrometry in Structural and Stereochemical Problems. XII. Structure of Vincamine and 1l–Methoxyvincamine.

Bull. Soc. Chim. France, 1082 (1962)
by M. Plat, D. D. Mann, J. LeMen, M.–M. Janot, H. Budzikiewicz, J. M. Wilson, L. J. Durham and C. Djerassi.

379.     Studies in Organic Sulphur Compounds. XIII. Lithium Aluminum Hydride Reduction of Episulphides to Olefins.

Chem. Ind., 1236 (1962)
by D. A. Lightner and C. Djerassi.

380.     Optical Rotatory Dispersion Studies. LXXVI. Inherently Dissymmetric Chromophores and Circular Dichroism.

J.A.C.S., 84, 2823 (1962)
By E. Bunnerberg, C. Djerassi, K. Mislow and A. Moscowitz.

381.     Alkaloid Studies. XXXV. The Structures of Stemmadenine and Condylocarpibe.

Tetrahedron Letters, 409 (1962)
by A. Sandoval, F. Walls, J. N. Shoolery, J. M. Wilson, H. Budzikiewicz and C. Djerassi.

382.     Alkaloid Studies. XXXVI. The Complete Absolute Configuration of the Diterpene Alkaloids of the Garrya and Atisine Groups and their Direct Correlation with the Phyllocladene–type Diterpenes.

J.A.C.S., 84, 2990 (1962)
by H. Vorbrueggen and Carl Djerassi.

383.     Alkaloid Studies. XXXVIII. Pilocereine–A Trimeric Cactus Alkaloid.

J.A.C.S., 84, 3210 (1962)
by C. Djerassi, H. W. Brewer, C. Clarke and L. J. Durham.

384.     Optical Rotatory Dispersion Studies. LXX. Anomalous Rotatory Dispersion of Xanthates: Application to Stereochemical Studies of Alcohols.

Acta Chem. Scand., 16, 1079 (1962)
by B. Sjoberg, D. J. Cram, L. Wolf and C. Djerassi.

385.     Optical Rotatory Dispersion Studies. LXXIII. Anomalous Rotatory Dispersion Curves Associated with Acylthioureas. Application to Stereochemical Studies of α—Substituted Carboxylic Acids.

Acta Chem. Scand., 16, 1147 (1962)
by C. Djerassi, K. Undheim and A.—M. Weidler.

386.     Mass Spectrometry in Structural and Stereochemical Problems. XIII. Echitamidine.

Tetrahedron Letters, 653 (1962)
by C. Djerassi, Y. Nakagawa, H. Budzikiewicz, J. M. Wilson, J. LeMen, J. Poisson and M.—M. Janot.

387.     Alkaloid Studies. XXXVII. The Structure of Aspidofiline.

Experientia, 18, 397 (1962)
by C. Djerassi, R. J. Owellen, J. M. Ferreira and L. D. Antonaccio.

388.     Mass Spectrometry in Structural and Stereochemical Problems. XI. The Structures of the Aspidosperma Alkaloids Spegazzinine and Spegazzinidine.

J.A.C.S., 84, 3480 (1962)

by C. Djerassi, H. W. Brewer, H. Budzikiewicz, O. O. Orazi and R. A. Corral.

389.     Terpenoids. LI. Isolation of Some New Cyclopropane-containing Triterpenes from Spanish Moss (Tillandsia  Usneoides).

J. Chem. Soc., 4034 (1962)

by C. Djerassi and R. McCrindle.

390.     Alkaloid Studies. XL. The Alkaloids of Aspidosperma Limae Woodson: Aspidolimidine, Aspidolimine, Demethoxypalosine and Aspidoccrpine

Chem. Ind., 1949 (1962)
by B. Gilbert, J. A. Brissolese, J. M. Wilson, H. Budzikiewicz, L. J. Durham and C. Djerassi.

391.     Alkaloid Studies. XLI. The Constitution of Lochneridine.

Chem. Ind., 1986 (1962)
by Y. Nakagawa, J. M. Wilson, H. Budzikiewicz and C. Djerassi.

392.     Optical Rotatory Dispersion Studies. LXXIV. Application of the Octant Rule to Some Structural and Stereochemical Problems.

J. Chem. Soc., 4929 (1962)
by C. Djerassi and W. Klyne.

393.     Mass Spectrometry in Structural and Stereochemical Problems. XV. Steroidal Sapogenins.

Monatsh., 93, 1033 (1962)
by H. Budzikiewicz, J. M. Wilson and C. Djerassi.

394.     Mass Spectrometry in Structural and Stereochemical Problems. XVI. The Structure of the Aspidosperma Alkaloid Aspidcalbine.

Tetrahedron Letters, 1001 (1962)
by C. Djerassi, L. D. Antonaccio, H. Budzikiewicz, J. M. Wilson and E. Gilbert.

395.     Mass Spectrometry in Structural and Stereochemical Problems. XIV. Steroids with One or Two Aromatic Rings.

J.A.C.S., 84, 4544 (1962)
by C. Djerassi, J. M. Wilson, H. Budzikiewicz and J. W. Chamberlin.

396.     Optical Rotatory Dispersion Studies. LXXVIII. Comparative Studies of Circular Dichroism and Rotatory Dispersion Curves.  Some Observations on Sulfur—Containing Chromophores.

J.A.C.S., 84, 4552 (1962)
by C. Djerassi, H. Wolf and E. Bunnenberg.

397.     Mass Spectrometry in Structural and Stereochemical Problems. XVII. The Structures of Four Alkaloids of Vinca Minor. (—)—Vincadifformine, Minovincine, Minovincinine and 16—Methoxyminovincine.

Bull. Soc. Chim. France, 2237 (1962)
by, M. Plat, J. LeMen, M.—M. Janot, H. Budzikiewicz, J. M. Wilson, L. J. Durham and C. Djerassi.

398.     Alkaloid Studies. XXXIX. The Occurrence of Dihydrocorynanthecl and Aricine in Aspidosperma Marcgravianum Woodson.

J. Org. Chem., 27, 4702 (1962)
by B. Gilbert, L. D. Antonaccio and C. Djerassi.

1963

399.     Mass Spectrometry in Structural and Stereochemical Problems. XXIII. Some Observations on the Mass Spectral Fragmentation of Δ1-­and Δ4-3-Keto Steroids.

Steroids, 1, 1 (1963)
by R. H. Shapiro, J.M. Wilson and Carl Djerassi.

400.     Optical Rotatory Dispersion Studies. LXXIX.
The Location of the n-π* Absorption Band of α-Iodoketones and Its Relation to Circular Dichroism and Optical Rotatory Dispersion.

J.A.C.S., 85. 324 (1963)
By C. Djerassi, H. Wolf and E. Bunnenberg.

401.     Optical Rotatory Dispersion Studies. LXXVII. Application of the Octant Rule to Some Structural and Stereochemical Problems: Part 2.

J. Chem. Soc., 2390 (1963)
By C. Djerassi and W. Klyne.

402.     Steroids. CCXXVII1. The Synthesis of Equilin.

Steroids, 1, 233 (1963)
By J. A. Zderic, H. Carpio, A. Bowers and C. Djerassi.

403.     The Structure of the Cactus Sterol Macdougalli (14α -Methyl-Δ8-Cholestene-3β,6α-Diol) —A Novel Link in Sterol Biogenesis.

J.A.C.S., 85, 835 (1963)
By C. Djerassi, J.C. Knight and D. I. Wil­kinson.

404.     Mass Spectrometry in Structural and Stereochemical Problems. XVIII. Fragmentation and Hydrogen Transfer Reactions After Electron Impact on α-Decalones. Synthesis of Poly-­deuterated α-Decalones.

J.A.C.S., 85, 941 (1963)
By E. Lund, H, Budzikiewicz, J. M. Wilson and C. Djerassi.

405.     Absolute Configuration and Optical Rotatory Dispersion of 3-Methylcycloheptanone and 4-Methylcycloheptanone.

J.A.C.S., 85, 949 (1963)

By C. Djerassi, B. F. Burrows, C. G. Overberger, T. Takekoshi, C. D. Gutsche and C. T. Chang

406.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXII. Determination of Mass Spectra of Non-Volatile Substances.

Experientia, 19, 211 (1963)
J.F. Lynch, J.M. Wilson, H. Budzikiewicz and C. Djerassi

407.     Optical Rotatory Dispersion Studies. LXXX. Inherently Dissymmetric Chromophores and Circular Dichroism. II.

J.A.C.S., 85, 1342 (1963)
By K. Mislow, E. Bunnenberg, R. Records, K. Wellman and C. Djerassi

408.     Mass Spectrometry in Structural and Stereo-chemical Problems. XX. Carapanaubine, a New Alkaloid from Aspidosperma Carapanauba and Some Observations on Mass Spectra of Oxindole Alkaloids.

J.A.C.S., 85, 1523 (1963)
By B. Gilbert, J.A. Brissolese, N. Finch, W.I. Taylor, H. Budzikiewicz, J.M. Wilson and C. Djerassi

409.     Mass Spectrometry in Structural and Stereo-chemical Problems XXI. Fragmentation and Hydrogen Transfer Reactions After Electron Impact on β-Decalones.

J.A.C.S., 85, 1528 (1963)
By E. Lund, H. Budzikiewicz, J.M. Wilson and C. Djerassi

410.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXVI. The Mass Spectra of Alkaloids of the Refractine-Pleiocarpine Class and the Structure of Aspidofractine, a Minor Alkaloid from Aspidosperma refractum Mart.

Helv. Chim. Acta, 46, 742 (1963)
By C. Djerassi, H. Budzikiewicz, R.J. Owellen, J.M. Wilson, W.G. Kump, D.J. LeCourq, A.R. Battersby and H. Schmid

411.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXVIII. Structure of Pseudo Akuammigine and of Picraline.

Bull. Soc. Chim. France, 646 (1963)
By L. Olivier, J. Lévy, J. LeMen, M.-M. Janot, C. Djerassi, H. Budzikiewicz, J.M. Wilson and L.J. Durham

412.     Bromination of 2-Oxosteroids.

Chem. Pharm. Bull. (Tokyo), 11, 465 (1963)
By T. Nakano, M. Hasegawa and C. Djerassi

413.     Optical Rotatory Dispersion Studies. LXXXII. Determination of the Stereochemistry and Con­formation of the Four Isomeric Cyanodihydro­-carvones by Optical Rotatory Dispersion and Dipole Moment Measurements.

J. Org. Chem., 28, 1632 (1963)
By C. Djerassi, R.A. Schneider, H. Vorbrueggen and N. L. Allinger

414.     Optical Rotatory Dispersion Studies. LXXXIV.
Studies of Conformational Mobility by Low‑
Temperature Circular Dichroism Measurements.

J.A.C.S., 85, 1870 (1963)
By K.M. Wellman, E. Bunnenberg and C. Djerassi

415.     Optical Rotatory Dispersion Studies. LXXXI.
Conformational Distortion in 2-Methylcyclo-­hexanones.

Tetrahedron, 19, 919 (1963)
By C. Beard, C. Djerassi, J. Sicher, F. Sĭpoš and M. Tichў

416.     Terpenoids. LII. Constitution and Absolute Configuration of Eremophilenolide.

Tetrahedron, 19, 1101 (1963)
By L. Novotny, J. Jizba, V. Herout, F. Šorm, L.H. zalkow, S. Hu and C. Djerassi

417.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXV. Mass Spectrometric In­vestigations in the Steroid, Terpenoid and Alkaloid Fields.

Pure and Appl. Chem., 6, 575 (1963)
By C. Djerassi

418.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXIV. A Study of the Hydrogen Transfer Reactions Accompanying Frag­mentation of 11-Keto Steroids. Synthesis of Deuterated Androstan-11-ones.

J.A.C.S., 85, 2091 (1963)
By D.H. Williams, J.M. Wilson, H. Budzikiewicz and C. Djerassi

419.     Mass Spectrometry in Structural and Stereo‑chemical Problems. XXVII. Mass Spectral Fragmentation Processes and Hydrogen Transfer Reactions of Amides and Amines.

J.A.C.S., 85, 2470 (1963)
By Z. Pelah, M.A. Kielczewski, J.M. Wilson, M. Ohashi, H. Budzikiewicz and C. Djerassi

420.     Studies in Organic Sulfur Compounds XIV. For­mation of Olefins on Desulfurization of Ethylene Thioketals by Raney Nickel.

J. Chem. Soc., 4046 (1963)
By C. Djerassi and D.H. Williams

421.     The Introduction of Deuterium into the C-19 Angular Methyl Group.

Steroids, 2, 125 (1963)
By C. Djerassi and M.A. Kielczewski

422.     Mass Spectrometry in Structural and Stereo-chemical Problems. XIX. Akuammicine and Related Alkaloids.

Tetrahedron, 19, 1265 (1963)
By H. Budzikiewicz, J.M. Wilson, C. Djerassi, J. Lévy, J. LeMen and M.-M. Janot

423.     Terpenoids LIII. Demonstration of Ring Confor­mational Changes in Triterpenes of the β-Amyrin Class Isolated from Stryphnodendron coriaceum.

J. Org. Chem., 28, 2390 (1963)
By B. Tursch, E. Tursch, I.T. Harrison, G. da Silva, H.J. Monteiro, B. Gilbert, W.B. Mors and C. Djerassi

424.     Optical Rotatory Dispersion Studies. LXXXV.
Circular Dichroism and Optical Rotatory Disper‑sion of the Nitrite and Nitro Chromophores.

J.A.C.S., 85, 2835 (1963)
By C. Djerassi, H. Wolf and E. Bunnenberg

 

425.     Mass Spectrometry in Structural and Stereochemical Problems. XXXI. Aporphines and Related Alkaloids.

J.A.C.S., 85, 2807 (1963)
By M. Ohashi, J.M. Wilson, H. Budzikiewicz, M. Shamma, W.A. Slusarchyk and C. Djerassi

426.     Unusual Chemical Shifts in the Nuclear Magnetic Resonance Spectra of 7- and 11- Keto Steroids.

J.A.C.S., 85, 2810 (1963)
By D.H. Williams, N.S. Bhacca and C. Djerassi

427.     Alkaloid Studies XLIV. The Structure of the Aspidosperma Alkaloid Compactinervine.

Experientia, 19, 467 (1963)
By C. Djerassi, Y. Nakagawa, J.M. Wilson, H. Budzikiewicz, B. Gilbert and L.D. Antonaccio

428.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXXVIII. Contribution to the Structure of Voacamine and Voacorine. Observations on the Mass Spectra of Vobasine and its Derivatives.

Bull. Soc. Chim. France, 1899 (1963)
By H. Budzikiewicz, C. Djerassi, F. Puisieux, F. Percheron and J. Poisson.

429.     Optical Rotatory Dispersion Studies. LXXXIII. Optical Rotatory Dispersion and Circular Dichroism of Episulfides and Trithiocarbonates.

Tetrahedron, 19, 1547 (1963)
By C. Djerassi, H. Wolf, D.A. Lightner, E. Bunnenberg, K. Takeda, T. Komeno and K. Kuriyama

430.     Alkaloid Studies XLII. The Structures of Dichotamine, 1-Acetyl-aspidoalbidine and 1-Acetyl-17-Hydroxy-aspidoalbidine: Three New Alkaloids from Vallesia dichotoma.

Tetrahedron Letters, 1731 (1963)
By K.S. Brown, H. Budzikiewicz and C. Djerassi

431.     Terpenoids LIV. Arborinol, a New Triterpene Type.

Liebigs Ann., 668, 57 (1963)
By H. Vorbrüggen, S.C. Pakrashi and C. Djerassi

432.     Optical Rotatory Dispersion Studies. LXXXVII. Recording and Nomenclature of Circular Dichroism.

Proc. Chem. Soc., 299 (1963)
By C. Djerassi and E. Bunnenberg

433.     Optical Rotatory Dispersion Studies. XCIII. Conformer Populations and Thermodynamic Data from Temperature-Dependent Circular Dichroism Measurements.

J.A.C.S., 85, 3515 (1963)
By A. Moscowitz, K. Wellman and C. Djerassi

434.     Mass Spectrometry in Structural and Stereo-chemical Problems. XXXII. Pentacyclic Tri-­terpenes.

J.A.C.S., 85, 3688 (1963)
By H. Budzikiewicz, J.M. Wilson and C. Djerassi

435.     Optical Rotatory Dispersion Studies. XCIV.
Some Effects of Solvation Upon Optically Active Molecules.

Proc. Natl. Acad. Sci., U.S., 50, 799 (1963)
By A. Moscowitz, K.M. Wellman and C. Djerassi

436.     Alkaloid Studies XLIII. The Alkaloids of Aspidosperma discolor.

Experientia, 19, 585 (1963)
By J.M.Ferreira, B.Gilbert, R.J.Owellen and C.Djerassi

437.     Mass Spectrometry in Structural and Stereo-chemical Problems XLVI. The Mass Spectro­metric Fragmentation of Steroidal Ethylene Ketals and Ethylene Thioketals.

Steroids, 2, 475 (1963)
By G. v.Mutzenbecher, Z.Pelah, D.H. Williams, H.Budzikiewicz and C.Djerassi

438.     Studies in Organic Sulfur Compounds XV. A Novel Base-Catalyzed Rearrangement of a Steroid β-Ketoxanthate.

Steroids, 2, 583 (1963)
By D.A. Lightner and C.Djerassi

439.     Mass Spectrometry in Structural and Stereo-chemical Problems XXIX. Mass Spectra of Isothiocyanates.

Acta Chem.Scand., 17, 2143 (1963)
By A. Kjaer, M.Ohashi, J.M.Wilson and C.Djerassi

440.     Mass Spectrometry in Structural and Stereo-chemical Problems XXXIII. Colchicine Alkaloids.

Tetrahedron, 19, 2225 (1963)
By J.M.Wilson, M.Ohashi, H.Budzikiewicz, F.Šantavў and C.Djerassi

441.     Mass Spectrometry in Structural and Stereo-chemical Problems XXXIV. Aromatic Methyl and Ethyl Ethers.

Tetrahedron, 19, 2233 (1963)
By Z.Pelah, J.M.Wilson, M.Ohashi, H. Budzikiewicz and C.Djerassi

442.     Mass Spectrometry in Structural and Stereo-chemical Problems XXXVI. The Mass Spectra of Stereoisomers of the Sarpagine-Akuammidine Group.

Tetrahedron, 19, 2241 (1963)
By M.Ohashi, H.Budzikiewicz, J.M.Wilson, C.Djerassi, J.Lévy, J.Gosset, J. LeMen and M.-M. Janot

443.     Mass Spectrometry in Structural and Stereo-chemical Problems XXXVII. Tropone and Tropo­lone Derivatives.

Tetrahedron, 19, 2247 (1963)
By J.M.Wilson, M.Ohashi, H.Budzikiewicz, C.Djerassi, S.Itô and T.Nozoe

444.     Synthesis of 15-Oxo-Steroids.

Proc.Chem.Soc., 377 (1963)
By C.Djerassi and G. v.Mutzenbecher

445.     Optical Rotatory Dispersion Studies LXXXIX.Optical Rotatory Dispersion Studies LXXXIX.The Octant Rule and the t-Butyl Group. Synthesis of Steroidal t-Butyl Ketones.

J. Am. Chem. Soc., 86, 78 (1964)
By C. Djerassi, P. A. Hart and E. J. Warawa.

446.     Optical Rotatory Dispersion Studies XC.
The Octant Rule and the Isopropyl Group. Synthesis of Steroidal Isoprapyl Ketones.

J. Am. Chem.. Soc., 86, 85 (1964)
By C. Djerassi, P. A. Hart and C. Beard.

447.     Mass Spectrometry in Structural and Stereo-chemical Problems XXXV. Mass Spectrometric Fragmentation and Hydrogen Transfer Reactions in 16-Keto Steroids.  A Novel Synthesis of Side Chain Labeled Cholestanes.

J. Am. Chem. Soc., 86, 269 (1964)
By C. Beard, J. M. Wilson, H. Budzikiewicz and C. Djerassi.

448.     Mass Spectrometry in Structural and Stereo-chemical Problems XLI.  Isotope Effect in Hydrogen Rearrangement Processes:  The Mass Spectra of Methyl Butyrate and Its γ-Mono-, Di-, and Trideuterio Analogs.

J. Am. Chem.. Soc., 86, 284 (1964)
By D. H. Williams, H. Budzikiewicz and C. Djerassi.

449.     Optical Rotatory Dispersion Studies LXXXVIII.Optical Rotatory Dispersion Studies LXXXVIII.Comparative Optical Rotatory Dispersion and Circular Dichroism Measurements of N-phthaloyl Amines and α-Amino Acids.

Ber., 97, 533 (1964)
By H. Wolf, E. Bunnenberg and C. Djerassi.

450.     Optical Rotatory Dispersion Studies XCI.
The Use of Low-Temperature Circular Dichroism Measurements for “Fingerprinting” of Steroidal Ketones.

J. Am. Chem. Soc., 86, 492 (1964)
By K. M. Wellman, R. Records, E. Bunnenberg and C. Djerassi.

451.     Optical Rotatory Dispersion Studies XCII.
Some Observations on the Conformation of cis-10-Methyl-2-decalones.

J. Am. Chem. Soc., 86, 465 (1964)
By C. Djerassi, J. Burakevich, J. W. Chamberlin, D. Elad, T. Toda and G. Stork.

452.     Mass Spectrometry in Structural and Stereo-chemical Problems XL. The Fragmentation Be­havior of Cyclohexanol and Its Deuteriated Analogs.

Monatsh., 95, 158 (1964)
By H. Budzikiewicz, Z. Pelah and C. Djerassi.

453.     Mass Spectrometry in Structural and Stereo-chemical Problems XLIV. Fragmentation of Monocyclic Ketones.

Monatsh., 95, 166 (1964)
By D. H. Williams, H. Budzikiewicz, Z. Pelah and C. Djerassi.

454.     Mass Spectrometry in Structural and Stereo-chemical Problems XLIII. Mass Spectrometric Fragmentation of Isohexylbromide and Five Deuteriated Derivatives.

J. Am. Chem. Soc., 86, 877 (1964)
By D. H. Williams, C. Beard, H. Bud­zikiewicz and C. Djerassi.

455.     Mass Spectrometry in Structural and Stereo-chemical Problems XLIX. The Mass Spectro­metric Fragmentation of 5α-androstan-ll-one. Synthesis of 19-d1-5α-androstan-11-one.

Steroids, 3, 259 (1964)
By D. H. Williams and C. Djerassi.

456.     Mass Spectrometry in Structural and Stereo-chemical Problems XXXIX. Tropane Alkaloids.

Tetrahedron, 20, 585 (1964)
By E. C. Blossey, H. Budzikiewicz, M. Ohashi, G. Fodor and C. Djerassi.

457.     Mass Spectrometry in Structural and Stereo-chemical Problems XLV. The Mass Spectro­metric Fragmentation Behavior of Isohexyl Cyanide and Its Deuterium Analogs.

J. Am. Chem. Soc., 86, 1386 (1964)
By R. Beugelmans, D. H. Williams, H. Budzikiewicz and C. Djerassi.

458.     Akuammiline--an Alkaloid from Picralima nitida.

Ann. Pharm. France, 22, 35 (1964)
By L. Olivier, J. Levy, J. LeMen, M.-M. Janot, H. Budzikiewicz and C. Djerassi.

459.     Optical Rotatory Dispersion Studies XCV.
Effect of Ring Size in Some Bicyclic Ketones.

J. Am. Chem. Soc., 86, 1755 (1964)
By C. Djerassi and J. E. Gurst.

460.     Mass Spectrometry in Structural and Stereo-chemical Problems LIV. The Structure of Tubulosine, A Novel Alkaloid from Pogonopus tubulosus.

J. Am. Chem. Soc., 86, 1895 (1964)
By P. Brauchli, V. Deulofeu, H. Bud­zikiewicz and C. Djerassi.

461.     Mass Spectrometry in Structural and Stereo‑chemical Problems LII. Structure and Mass Spectrometric Fragmentation of Vindolinine.

Helv. Chim. Acta, 47, 827 (1964)
By C. Djerassi, M. Cereghetti, M. Plat, H Budzikiewicz, M.-M. Janot and J. LeMen.

462.     Macrolide Antibiotics XIII. Nystatin. Biosynthetic Definition of Some Structural Features.

TetrahedronLetters,1485(1964)
By A. J. Birch, C. W. Holzapfel, R. W. Rickards, C. Djerassi, M. Suzuki, J. Westley, J. D. Dutcher and R. Thomas.

463.     Macrolide Antibiotics XIV. Nystatin. Chemistry and Partial Structure of the Antibiotic.

Tetrahedron Letters, 1491 (1964)
By A. J. Birch, C. W. Holzapfel, R. W. Rickards, C. Djerassi, M. Suzuki, J. W. Westley, J. D. Dutcher and P. C. Seidel.

464.     Alkaloid Studies XLVI. The Alkaloids of Aspidosperma Obscurinervium Azembuja: A New Class of Heptacyclic Alka'oids.

J. Am. Chem. Soc., 86, 2451 (1964)
By K. S. Brown and C. Djerassi.

465.     Mass Spectrometry in Structural and Stereo‑chemical Problems XLVII. Some Observations on Mass Spectra of Pseudoindoxyl Alkaloids.

J. Am. Chem. Soc., 86, 2620 (1964)
By N. Finch, I. Hsiu-Chu Hsu, W. I. Taylor, H. Budzikiewicz and C. Djerassi.

466.     Mass Spectrometry in Structural and Stereo-chemical Problems XLVIII. A Study of the Hydrogen Transfer Reactions Accompanying Fragmentation Processes of 1-Keto Steroids. Synthesis of Deuterated 5α-Androstan-l-ones.

J. Am. Chem. Soc., 86, 2623 (1964)
By H. Powell, D. H. Williams, H. Budzikiewicz and C. Djerassi.

467.     Pyrroles and Related Compounds. Part IV.
Mass Spectrometry in Structural and Stereo-chemical Problems. Part XXX. Mass Spectra of Monocyclic Derivatives of Pyrrole.

J. Chem. Soc., 1949 (1964)
By H. Budzikiewicz, C. Djerassi, A. H. Jackson, G. W. Kenner, D. J. Newman and J. M. Wilson.

468.     Mass Spectrometry in Structural and Stereo-chemical Problems. L. Fragmentation and Hydrogen Migration Reactions of α,β-Un­saturated 3-Keto Steroids.

J. Am. Chem. Soc., 86, 2825 (1964)
By R. H. Shapiro and C. Djerassi.

469.     Mass Spectrometry in Structural and Stereo‑chemical Problems. LI. Mass Spectral and Enolization Studies on 7-Keto-5α-androstanes.

J. Am. Chem. Soc., 86, 2832 (1964)
By R. Beugelmans, R. H. Shapiro, Lois J. Durham, D. H. Williams, H. Bud­zikiewicz and C. Djerassi.

470.     Mass Spectrometry in Structural and Stereo-chemical Problems. LIII. Fragmentation and Hydrogen Transfer Reactions of a Typical 3-Keto Steroid, 5α-Androstan-3-one.

J. Am. Chem. Soc., 86, 2837 (1964)
By R. H. Shapiro, D. H. Williams, H. Budzikiewicz and C. Djerassi.

471.     Optical Rotatory Dispersion Studies LXXXVI. Preparation, Anomalous Rotatory Dispersion and Circular Dichroism of Optically Active Trithiones.

Ann. 674, 62 (1964)
By H. Wolf, E. Bunnenberg, C. Djerassi, A. Luttringhaus and A. Stockhausen.

472.     Alkaloid Studies XLVII. The Structures of Five New Aspidosperma Alkaloids Related to Uleine.

Experientia 20, 363 (1964)
By M. Ohashi, J. A. Joule, B. Gilbert and C. Djerassi.

473.     Alkaloid Studies XLV. Mass Spectrometry in Structural and Stereochemical Problems XLII. Some Aspects of the Chemistry and Mass Spectrometry of Uleine.

J. Chem. Soc., 2777 (1964)
By J. A. Joule and C. Djerassi.

474.     Mass Spectrometry in Structural and Stereo-chemical Problems LV. The Mass Spectrometric Fragmentation of Ethylene Ketals.

J. Am. Chem. Soc., 86, 3722 (1964)
By Z. Pelah, D. H. Williams, H. Budzikiewicz and C. Djerassi.

475.     Mass Spectrometry in Structural and Stereo‑chemical Problems LVI. Fragmentation and Hydrogen Transfer Reaction of 4,4-Dimethy1-5α-Androstan-3-one and Related Ketones.

Tetrahedron, 20, 1987 (1964)
By R. H. Shapiro and C. Djerassi.

476.     Optical Rotatory Dispersion Studies XCVI. Applications of Optical Rotatory Dispersion and Circular Dichroism in Stereochemistry.

Proc. Chem. Soc., 314 (1964)
By C. Djerassi.

477.     Mass Spectrometry in Structural and Stereo‑chemical Problems LVII. Isotope Labeling and Mass Spectrometry of Natural Products.

Pure Appl. Chem., 9, 159 (1964)
By C. Djerassi.

478.     Alkaloid Studies XLIX. The Structure of Vallesamin and 0-Acetyl-Vallesamin.

Helv. Chim. Acta, 47, 2072 (1964)
By A. Walser and C. Djerassi.

479.     New Steroids from Cactus Wilcoxia Viperina.

Ber. 97, 3118 (1964)
By C. Djerassi, J. C. Knight and H. Brockmann.

480.     Alkaloid Studies LI. The Structure of Aspidodasycarpine.

Tetrahedron Letters, 3899 (1964)
By M. Ohashi, J. A. Joule and C. Djerassi.

 

481.     Mass Spectrometry in Structural and Stereo-chemical Problems LVIII. A Study of the Fragmentation Processes of Some Lactams.

J. Am. Chem. Soc., 86, 5536 (1964)
By A. M. Duffield, H. Budzikiewicz and C. Djerassi.

482.     Mass Spectrometry in Structural and Stereo-chemical Problems LIX. Mechanism of the Formal Loss of Acetone from 2-0xo-5α-Steroids.

J. Am. Chem. Soc., 86, 5542 (1964)
By J. E. Gurst and C. Djerassi.

483.     Studies in Relation to Biosynthesis XXXV. Macrolide Antibiotics XII. Methymycin.

J. Chem. Soc., 5274 (1964)
By A. J. Birch, C. Djerassi, J. D. Dutcher, J. Majer, D. Perlman, E. Pride, R. W. Rickards and P. J. Thomson.

484.     Optical Rotatory Dispersion Studies XCVII.
Anomalous Rotatory Dispersion and Circular Dichroism Curves Associated with Thionamides. Application to Stereochemical Studies of Carboxylic Acids.

J. Am. Chem. Soc., 87, 51 (1965)
By J. V. Burakevich and C. Djerassi.

485.     Optical Rotatory Dispersion Studies XCVIII. The Conformation of the 17-Acetyl Group in Steroids and Its Correlation with Variable-Temperature Circular Dichroism.

J. Am. Chem. Soc., 87, 60 (1965)
By K. M. Wellman and C. Djerassi.

486.     Optical Rotatory Dispersion Studies XCIX. Super­posed Multiple Cotton Effects of Saturated Ketones and Their Significance in the Circular Dichroism Measurement of (-)-Menthone.

J. Am. Chem. Soc., 87, 66 (1965)
By K. M. Wellman, P. H. A. Laur, W. S. Briggs, A. Moscowitz and C. Djerassi.

487.     Optical Rotatory Dispersion Studies C. Variable-Temperature Circular Dichroism Studies of Ring-Conformational and Rotational Equilibria in Cyclohexanones.

J. Am. Chem. Soc., 87, 73 (1965)
By K. M. Wellman, W.S. Briggs and C. Djerassi.

488.     Optical Rotatory Dispersion Studies CI. Rotatory Dispersion Curves of Cyclopropyl-Ketones and Epoxy-Ketones.

Tetrahedron, 21, 163 (1965)
By C. Djerassi, W. Klyne, T. Norin, G. Ohloff and E. Klein.

489.     Mass Spectrometry in Structural and Stereochemical Problems LX. The Electron Impact Induced Fragmentation of Steroidal Dimethylamines.

J. Am. Chem. Soc., 87, 574 (1965)
By Z. Pelah, D. H. Williams, H. Budzikiewicz and C. Djerassi.

490.     Mass Spectrometry in Structural and Stereochemical Problems LXII. Fragmentation and Hydrogen Transfer Reactions of β-Hydrindanones. Synthesis of Deuterated β-Hydrindanones.

J. Am. Chem. Soc., 87, 580 (1965)
By J. Karliner, H. Budzikiewicz and C. Djerassi.

491.     Studies in Organic Sulfur Compounds XVI. Synthesis and Reactions of Steroid Episulfides.

Tetrahedron, 21, 583 (1965)
By D. A. Lightner and C. Djerassi.

492.     Mass Spectrometry in Structural and Stereochemical Problems LXIII. Hydrogen Rearrangements Induced by Electron Impact on N-n-butyl- and N-n-pentylpyrroles.

J. Am. Chem. Soc., 87, 805 (1965)
By A. M. Duffield, R. Beugelmans, H. Budzikiewicz, D. A. Lightner, D. H. Williams and C. Djerassi.

493.     Mass Spectrometry in Structural and Stereochemical Problems LXIV. A Study of the Fragmentation Processes of Some Cyclic Amines.

J. Am. Chem. Soc., 87, 810 (1965)
By A. M. Duffield, H. Budzikiewicz, D. H. Williams and C. Djerassi.

494.     Mass Spectrometry in Structural and Stereochemical Problems LXV. Synthesis and Fragmentation Behavior of 15-Keto Steroids. The Importance of Interatomic Distance in the McLafferty Rearrangement.

J. Am. Chem. Soc., 87, 817 (1965)
By C. Djerassi, G. von Mutzenbecher, J. Fajkos, D. H. Williams and H. Budzikiewicz.

495.     The Structure of the Cactus Sterol Peniocerol (cholest-8-ene-3β,6α-diol).

J. Chem. Soc., 1160 (1965)
By C. Djerassi, R. D. H. Murray and R. Villotti.

496.     Structure of Tomatillidine.

J. Org. Chem., 30, 754 (1965)
By E. Bianchi, C. Djerassi, H. Budzikiewicz and Y. Sato.

497.     Mass Spectrometry in Structural and Stereochemical Problems LXVI. Mass Spectral Fragmentation of 6,7-Dimethoxycoumarin.

J. Org. Chem., 30, 955 (1965)
By R. H. Shapiro and C. Djerassi.

498.     Magnetic Circular Dichroism Studies: A Preliminary Report.

Proc. Natl. Acad. Sci., 53, 579 (1965)
By D. A. Schooley, E. Bunnenberg and C. Djerassi.

499.     Mass Spectrometry in Structural and Stereochemical Problems LXIX. Methyl Migration in an Electron Impact Induced Fragmentation.

J. Am. Chem. Soc., 87, 1398 (1965)
By F. Komitsky, Jr., J. E. Gurst and C. Djerassi.

500.     Alkaloid Studies LII. The Alkaloids cf Vallesia Dichotoma.

Helv. Chim. Acta, 48, 391 (1965)
By A. Walser and C. Djerassi.

501.     Structure and Absolute Configuration of Picraline, Pseudo-akuammigine, Akuammine and Akuammiline.

Bull. Soc. Chim, France, 868 (1965)
By L. Olivier, J. Levy, J. LeMen, M.-M Janot, H. Budzikiewicz and C. Djerassi.

502.     Mass Spectrometry in Structural and Stereochemical Problems LXI. The Mass Spectrometric Fragmentation Behavior of Anthracyclinones.

Ber., 98, 1260 (1965)
By H. Brockmann, Jr., H. Budzikiewicz, C. Djerassi, H. Brockmann and J. Niemeyer.

503.     Alkaloid Studies L. The Alkaloids of Twelve Aspidosperma Species.

Tetrahedron, 21, 1141 (1965)
By B. Gilbert, A. P. Duarte, Y. Nakagawa, J. A. Joule, S. E. Flores, J. A. Brissolese, J. Campello, E. P. Carrazzoni, R. J. Owellen, E. C. Blossey, K. S. Brown and C. Djerassi.

504.     Optical Rotatory Dispersion Studies CII. Optical Rotatory Dispersion and Circular Dichroism of Thiolacetates.

Tetrahedron, 21, 1203 (1965)
By K. Takeda, K. Kuriyama, T. Komeno, D. A. Lightner, R. Records and C. Djerassi.

505.     Optical Rotatory Dispersion Studies CIII. Optical Rotatory Dispersion and Circular Dichroism of Twisted Sulfur-Containing Chromophoric Systems.

Tetrahedron, 21, 1581 (1965)
By D. A. Lightner, C. Djerassi, K. Takeda, K. Kuriyama and T. Komeno.

506.     Mass Spectrometry in Structural and Stereochemical Problems LXX. A Study of the Fragmentation Processes of Some Five-Membered N-Alkyl Lactams and N-Alkyl Succinimides.

J. Am. Chem. Soc., 87, 2913 (1965)
By A. M. Duffield, H. Budzikiewicz and C. Djerassi.

507.     Mass Spectrometry in Structural and Stereochemical Problems LXXI. A Study of the Influence of Different Heteroatoms on the Mass Spectrometric Fragmentation of Five-Membered Heterocycles.

J. Am. Chem. Soc., 87, 2920 (1965)
By A. M. Duffield, H. Budzikiewicz and C. Djerassi.

508.     Mass Spectrometry in Structural and Stereochemical Problems LXXII. A Study of the Fragmentation Processes of Some Tobacco Alkaloids.

J. Am. Chem. Soc., 87, 2926 (1965)
By A. M. Duffield, H. Budzikiewicz and C. Djerassi.

 

509.     Mass Spectrometry in Structural and Stereochemical Problems LXVII. Retro-Diels-Alder Decomposition of Organic Molecules under Electron Impact.

Tetrahedron, 21, 1855 (1965)
By H. Budzikiewicz, J. I. Brauman and C. Djerassi.

510.     Mass Spectrometry in Structural and Stereochemical Problems LXVIII. Mass Spectrometric Investigations of Hashish Constituents.

Tetrahedron, 21, 1881 (1965)
By H. Budzikiewicz, R. T. Aplin, D. A. Lightner, C. Djerassi, R. Mechoulam and Y. Gaoni.

511.     Alkaloid Studies LIII. The Structures of Nine New Alkaloids from Aspidosperma Dasycarpon A. DC.

Tetrahedron, 21, 1717 (1965)
By J. A. Joule, M. Ohashi, B. Gilbert and C. Djerassi.

512.     Mass Spectrometry in Structural and Stereochemical Problems LXXIII. The Negative Ion Mass Spectra of Some Simple Organic Compounds.

J. Am. Chem. Soc., 87, 3180 (1965)
By R. T. Aplin, H. Budzikiewicz and C. Djerassi.

513.     Mass Spectrometry in Structural and Stereochemical Problems LXXVIII. Steroidal Δ4-3,6-Diketones.

Steroids, 6, 1 (1965)
By C. Djerassi, J. Karliner and R. T. Aplin.

514.     Alkaloid Studies LIV. Structure of Deoxytubulosine and Interconversion with Tubulosine.

Chem. Commun., 317 (1965)
By H. Monteiro, H. Budzikiewicz, C. Djerassi, R. R. Arndt and W. H. Baarschers.

515.     Recent Applications of Mass Spectrometry in Steroid Chemistry.

Proceed. 1st Internat. Congress on Hormonal Steroids, Academic Press, New York, 1965, Vol. 2, pp. 3-10
By C. Djerassi, H. Budzikiewicz and J. M. Wilson.

516.     Terpenoids LVI. The Complete Structure of the Triterpene Arborinol.

Tetrahedron Letters, 39, 3433 (1965)
By Olga Kennard, L. Riva di Sanseverino, H. Vorbrüggen and C. Djerassi.

517.     The Bromination of 15-Keto Steroids.

Steroids, 6, 239 (1965)
By C. Djerassi, J. Fajkos and A. R. Van Horn.

518.     Alkaloid Studies XLVIII. The Structure of Apparicine, a Novel Aspidosperma Alkaloid.

J. Chem. Soc., 4773 (1965)
By J. A. Joule, H. Monteiro, L. J. Durham, B. Gilbert and C. Djerassi.

 

519.     New Alkaloids from Vinca Major.

Bull. Soc. Chim., France, 2497 (1965)
By M. Plat, R. Lemay, J. LeMen, M.-M. Janot, C. Djerassi and H. Budzikiewicz.

520.     Mass Spectrometry in Structural and Stereochemical Problems LXXVI. The Mass Spectra of Porphyrins.

Tetrahedron, 21, 2913 (1965)
By A. H. Jackson, G. W. Kenner, K. M. Smith, R. T. Aplin, H. Budzikiewicz and C. Djerassi.

521.     Mass Spectrometry in Structural and Stereochemical Problems LXXXIX. Exchange of Enolizable Hydrogens in the Inlet System of the Mass Spectrometer.

Chem. Ind. (London), 1697 (1965)
By H. Budzikiewicz and C. Djerassi.

522.     Mechanism of Reduction of Tosylhydrazones with Complex Metal Hydrides.

Ber., 98, 3236 (1965)
By M. Fischer, Z. Pelah, D. H. Williams and C. Djerassi.

523.     Mass Spectrometry in Structural and Stereochemical Problems LXXIV. A Study of the Fragmentation of N-Acylpyrrolidines.

J. Am. Chem. Soc., 87, 4554 (1965)
By A. M. Duffield and C. Djerassi.

524.     Mass Spectrometry in Structural and Stereochemical Problems LXXV. Occurrence of Alkyl Rearrangements in the Fragmentation of Some Formaldehyde Acetals.

J. Am. Chem. Soc., 87, 4559 (1965)
By P. Brown, C. Djerassi, G. Schroll, H. J. Jakobsen and S.-O. Lawesson.

525.     Conformational Studies of cis-lO-Methyl-2-Decalones.

Experientia, 21, 565 (1965)
By W. G. Dauben, R. M. Coates, N. D. Vietmeyer, L. J. Durham and C. Djerassi.

526.     Alkaloid Studies LV. 19-Dehydroyohimbine, a Novel Alkaloid from Aspidosperma Pyricollum.

Experientia, 21, 566 (1965)
By R. R. Arndt and C. Djerassi.

527.     Mass Spectrometry in Structural and Stereochemical Problems LXXIX. Aliphatic and Alicyclic Nitro Compounds.

J. Am. Chem. Soc., 87, 4888 (1965)
By R. T. Aplin, M. Fischer, D. Becher, H. Budzikiewicz and C. Djerassi.

528.     Mass Spectrometry in Structural and Stereochemical Problems LXXXI. Stereospecificity in a Hydrogen-Transfer Reaction Characteristic of 6-Keto Steroids.

J. Am. Chem. Soc., 87, 4892 (1965)
By C. Djerassi, R. H. Shapiro and M. Vandewalle.

529.     Mass Spectrometry in Structural and Stereochemical Problems LXXXII. A Study of the Fragmentation of Some Amaryllidaceae Alkaloids.

J. Am. Chem. Soc., 87, 4902 (1965)
By A. M. Duffield, R. T. Aplin, H. Budzikiewicz, C. Djerassi, C. F. Murphy and W. C. Wildman.

530.     Mass Spectrometry in Structural and Stereochemical Problems XCIV. Steroidal Δ16 -20 Ketones and Δ9(II)-12-Ketones.

Steroids, 6, 493 (1965)
By L. Tökés and C. Djerassi.

531.     Mass Spectrometry in Structural and Stereochemical Problems XCVIII. Absence of Methyl Migration in 2,2,8,8-Tetramethylnonan-5-one.

Chem. Comm., 578 (1965)
By R. R. Arndt and C. Djerassi.

532.     Studies in Organic Sulfur Compounds XVII. The Synthesis of Previously Inaccessible Acylated Enamines by Desulfur­ization of Thiazolidines.

J. Chem. Soc., 6253 (1965)
By N. S. Crossley, C. Djerassi and M. A. Kielczewski.

533.     Optical Rotatory Dispersion Studies CIV. Low Temperature Circular Dichroism Behavior of Various Chromophoric Derivatives of Alcohols and Amines.

Tetrahedron, 21, 3455 (1965)
By W. S. Briggs and C. Djerassi.

534.     Mass Spectrometry in Structural and Stereochemical Problems LXXX. Mass Spectrometric Fragmentation of Nitrophenylhydrazones.

Nature, 208, 1314 (1965)
By C. Djerassi and S. D. Sample.

535.     Mass Spectrometry in Structural and Stereochemical Problems LXXXIV. The Nature of the Cyclic Transition State in Hydrogen Rearrangements of Aliphatic Ethers.

J. Am. Chem. Soc., 87, 5747 (1965)
By C. Djerassi and C. Fenselau.

536.     Mass Spectrometry in Structural and Stereochemical Problems LXXXV. The Nature of the Cyclic Transition State in Hydrogen Rearrangements of Aliphatic Amines.

J. Am. Chem. Soc., 87, 5752 (1965)
By C. Djerassi and C. Fenselau.

537.     Mass Spectrometry in Structural and Stereochemical Problems LXXXVI. The Nature of the Hydrogen Transfer Reactions in Butyl Propionate, Benzoate and Phthalate.

J. Am. Chem. Soc., 87, 5756 (1965)
By C. Djerassi and C. Fenselau.

 

538.  Mass Spectrometry in Structural and Stereochemical Problems. Two

      Deuterated Isothiocyanates.

                  Acta. Chem. Scand., 19, 2438 (1965)

         By E. Bach, A. Kjaer, R. H. Shapiro and C. Djerassi.

 

539.     Mass Spectrometry in Structural and Stereochemical Problems LXXVII. Influence of Restricted Rotation as well as other Energetic Factors on the McLafferty Rearrangement of Ketones.

Chem. Ber., 99, 35 (1966)
By H. Fritz, H. Budzikiewicz and C. Djerassi.

540.     Mass Spectrometry in Structural and Stereochemical Problems C. Suppression of McLafferty Rearrangements in the Mass Spectrometric Fragmentation of Even-Electron Systems.

Chem. Comm., 12 (1966)
By C. Djerassi, M. Fischer and J. B. Thomson.

541.     Mass Spectrometry in Structural and Stereochemical Problems LXXXVIII. Rearrangements of Simple Terpenes on Electron Impact.

J. Org. Chem., 31, 115 (1966)
By D. S. Weinberg and C. Djerassi.

542.     Mass Spectrometry in Structural and Stereochemical Problems XCIII. Further Observations on the Importance of Interatomic Distance in the McLafferty Rearrangement. Synthesis and Fragmentation Behavior of Deuterium Labeled 12-Keto Steroids.

J. Am. Chem. Soc., 88, 536 (1966)

By C. Djerassi and L. Tökés.

543.     Terpenoids LV. Studies in the Chemistry of the Eremophilane Sesquiterpenes.

Tetrahedron, 22, 337 (1966)
By L. H. Zalkow, A. M. Shaligram, Shih-En Hu and C. Djerassi.

544.     The Structure of the Cactus Sterol Macdougallin (14α-Methyl-Δ8-cholestene-3β, 6α-diol). A Novel Link in Sterol Biogenesis.

J. Am. Chem. Soc., 88, 790 (1966)
By J. C. Knight, D. I. Wilkinson and C. Djerassi.

545.     Mass Spectrometry in Structural and Stereochemical Problems CIII. Electron Impact Induced Methyl Migration in Some 2-Arylidene-l-Decalones.

J. Am. Chem. Soc., 88, 860 (1966)
By C. Djerassi, A. M. Duffield, F. Komitsky, Jr. and L. Tökés.

546.     Steroid Oral Contraceptives.

Science, 151, 1055 (1966)
By C. Djerassi.

 

547.     Mass Spectrometry in Structural and Stereochemical Problems LXXXVII. Possibility of Methyl Migrations in Aromatic Compounds.

Chem. Ber., 99, 750 (1966)
By M. Fischer and C. Djerassi.

548.     Mass Spectrometry in Structural and Stereochemical Problems XCI. The Electron Impact Induced Elimination of Water from 3-Hydroxy Steroids.

J. Org. Chem., 31, 710 (1966)
By J. Karliner, H. Budzikiewicz and C. Djerassi.

549.     Optical Rotatory Dispersion Studies CV. The Absolute Configuration of Rosonono and Rosolo Lactones.

J. Chem. Soc. (C), 624 (1966)
By C. Djerassi, B. Green, W. G. Whalley and C. G. DeGrazia.

550.     Mass Spectrometry in Structural and Stereochemical Problems LXXXIII. Partial Structure of Vobtusine.

Tetrahedron, 22, 1075 (1966)
By J. Poisson, M. Plat, H. Budzikiewicz, L. J. Durham and C. Djerassi.

551.     Alkaloid Studies LVI. The Constitution of Vallesiachotamine.

J. Am. Chem. Soc., 88, 1792 (1966)
By C. Djerassi, H. J. Monteiro, A. Walser and L. J. Durham.

552.     Mass Spectrometry in Structural and Stereochemical Problems CIX. The Non-Specificity of Hydrogen Re­arrangements in Aryl Alkyl Ethers.

J. Am. Chem. Soc., 88, 1840 (1966)

By J. K. MacLeod and C. Djerassi.

553.     Mass Spectrometry in Structural and Stereochemical Problems CX. The Course of the Electron Impact Induced Dehydrochlorination of Primary Alkyl Chlorides.

Chem. Comm., 193 (1966)
By A. M. Duffield, S. D. Sample and C. Djerassi.

554.     Mass Spectrometry in Structural and Stereochemical Problems XCII. Further Studies on the McLafferty Rearrangement of Aliphatic Ketones

Tetrahedron, 22, 1391 (1966)
By H. Budzikiewicz, C. Fenselau and C. Djerassi

555.     Mass Spectrometry in Structural and Stereochemical Problems CVIII. Dueterium Isotope Effects in Site-Specific Mass Spectrometric Rearrangement Processes

Tetrahedron Letters, 19, 2183 (1966)
By J. K. MacLeod and Carl Djerassi

556.     Mass Spectrometry in Structural and Stereochemical Problems CI. A Study of the Fragmentation of Some Azabicyclo Lactams

J. Org. Chem., 31, 1599 (1966)
By A. M. Duffield, Carl Djerassi, Lawrence Wise and Leo A. Paquette

557.     Mass Spectrometry in Structural and Stereochemical Problems CIV. The Nature of the Cyclic Transition State in Hydrogen Rearrangements of Aliphatic Sulfides

J. Am. Chem. Sac., 88, 1937 (1966)
By Shelia Sample and C. Djerassi

558.     Mass Spectrometry in Structural and Stereochemical Problems XCV. A Study of the Fragmentation Processes of Same Pyridones on Electron Impact

Acta Chem. Scand., 20, 361 (1966)
By A. M. Duffield, C. Dierassi, G. Schroll and S.-0. Lawesson

559.     Mass Spectrometry in Structural and Stereochemical Problems XCVI. Mass Spectrometric Fragmentation of Azomethines

Chem. Ber., 99, 1541 (1966)
By M. Fischer and C. Djerassi

560.     Mass Spectrometry in Structural and Stereochemical Problems CV1. Occurrence of Alkyl and Aryl Rearrangements in the Fragmentation of Some Organic Carbonates

J. Am, Chem. Soc., 88, 2469 (1966)
By Peter Brown and Carl Djerassi

561.     Terpenoids LVII. Mass Spectrometry in Structural and Stereochemical Problems CV. Mass Spectral and Nuclear Magnetic Resonance Studies of Pentacyclic Triterpene Hydrocarbons

J. Org. Chem., 31, 1945 (1966)
By J. Karliner and C. Djerassi

562.     Alkaloid Studies LVII. Indole Alkaloids of the Aspidospermine Class. "Phytochimie et Plantes Medicinales des Terres du Pacifique".

C.N.R.S., Paris, (1966), pp. 191-204
By C. Djerassi.

563.     Mass Spectrometry in Structural and Stereochemical Problems CVII. Fragmentation Behavior of Semi­carbazones.

Chem. Ger., 99, 2284 (1966)

By D. Becher, S. D. Sample and C. Djerassi.

564.     Mass Spectrometry in Structural and Stereochemical Problems CXIX. Interaction of Remote Functional Groups in Mass Spectrometry.

J. Am. Chem. Soc., 88, 3883 (1966)
By M. M. Green, D. S. Weinberg and C. Djerassi.

565.     Mass Spectrometry in Structural and Stereochemical Problems CXIV. Electron Impact Induced Rearrange­ment of Thiocarbonates, Carbamates and Thio­carbamates.

J. Am. Chem. Soc., 88, 4049 (1966)
By J. B. Thomson, P. Brown and C. Djerassi.

 

566.     Mass Spectrometry in Structural and Stereochemical Problems XCVII. A Study of the Fragmentation Processes of Oximes.

Tetrahedron, 22, Suppl. 7, 145 (1966)
By D. Goldsmith, D. Becher, S. Sample and C. Djerassi.

567.     Mass Spectrometry in Structural and Stereochemical Problems CII. Study on the Structure of Cincho­phyllamine and Isocinchophythamine.

Bull. Soc. Chim. France, 2309 (1966)
By P. Potier, C. Korn, J. LeMen, M.-M. Janot, H. Budzikiewicz and C. Djerassi.

568.     Optical Rotatory Dispersion Studies CVI. Low Temperature Circular Dichroism of Various Polysub­stituted Cyclopentanones.

Bull. Soc. Chim. France, 2378 (1966)
By C. Djerassi, R. Records, C. Ouannes and J. Jacques.

569.     Selective Reduction of Steroids by Homogeneous Catalytic Hydrogenation.

J. Am. Chem. Soc., 88, 4537 (1966)
By C. Djerassi and J. Gutzwiller.

570.     Mass Spectrometry in Structural and Stereochemical Problems CXI. The Mass Spectrometric Fragmentation of Substituted Naphthoquinones and its Application to Structural Elucidation of Echinoderm Pigments.

J. Org. Chem., 31, 3650 (1966)
By D. Becher, C. Djerassi, R. E. Moore, H. Singh and P. J. Scheuer.

571.     Mass Spectrometry in Structural and Stereochemical Problems CXII. Fragmentation of Two Bicyclic Amines on Electron Impact.

J. Org. Chem., 31, 3832 (1966)
By D. S. Weinberg and C. Djerassi.

572.     Mass Spectrometry in Structural and Stereochemical Problems CXIII. Specific Hydrogen Rearrangements in the Fragmentation of Hydrazones.

J. Org. Chem., 31, 3661 (1966)
By D. Goldsmith and C. Djerassi.

573.     Mass Spectrometry in Structural and Stereochemical Problems CXVIII. Aliphatic Epoxides.

Tetrahedron, Suppl. 8, Part 1, 241 (1966)
By P. Brown, J. Kossanyi and C. Djerassi.

574.     Magnetic Circular Dichroism Studies II. Preliminary Results with Some Aromatic Compounds.

Proc. Natl. Acad. Sci., 56, 1377 (1966)
By D. A. Schooley, E. Bunnenberg and C. Djerassi.

575.     Mass Spectrometry in Structural and Stereochemical Problems CXXI. Fragmentation and Hydrogen Rearrangements in 4-Ketosteroids.

Helv. Chim. Acta, 49, 2108 (1966)
By J. Gutzwiller and C. Djerassi.

576.     Mass Spectrometry in Structural and Stereochemical Problems CXV. Mass Spectra of tert-Butyl Ethers.

Arkiv Kemi, 26, 199 (1966)
By H. J. Jakobsen, G. Schroll, S.-O. Lawesson, D. A. Lightner, A. M. Duffield and C. Djerassi.

577.     Mass Spectrometry in Structural and Stereochemical Problems CXVI. The Fragmentation of Some Orthoesters and Orthothioesters upon Electron Impact.

Arkiv Kemi, 26, 279 (1966)
By G. Schroll, H. J. Jakobsen, S.-O. Lawesson, P. Brown and C. Djerassi.

578.     Mass Spectrometry in Structural and Stereochemical Problems CXX. Electron-Impact-Induced Fragmentation Processes of Methoxycarbonylhydrazones.

J. Org. Chem., 31, 4050 (1966)
By J. K. MacLeod, D. Becher and C. Djerassi.

579.     Optical Rotatory Dispersion Studies CVIII. Anomalous Optical Rotation and Circular Dichroism of N-Thioacylated α-Amino Acids and Derivatives in Various Solvents.

Acta Chem. Scand., 20, 2781 (1966)
By E. Bach, A. Kjaer, R. Dahlbom, T. Walle, B. Sjöberg, E. Bunnenberg, C. Djerassi and R. Records.

580.     Optical Rotatory Dispersion Studies CIX, An Octant Rule for the Azide Chromophore,

J. Am. Chem. Soc., 89, 347 (1967)
By C. Djerassi, A. Moscowitz, K. Ponsold and G. Steiner.

581.     Mass Spectrometry in Structural and Stereochemical Problems XC. Mass Spectra of Linear Di-, Tri- and Tetrapyrrolic Compounds.

Tetrahedron, 23, 603 (1967)
By A. N. Jackson, G, W. Kenner, H. Budzikiewicz, C. Djerassi and J. M. Wilson.

582.     Terpenoids LVIII. Griseogenin, a New Triterpenoid Sapogenin of the Sea Cucumber Halodeima Grisea L.

Tetrahedron, 23, 761 (1967)
By B. Tursch, I. S. D. Guimaraes, B. Gilbert, R. T. Aplin, A. M. Duffield and C. Djerassi.

583.     Terpenoids LIX. The Structure of Jegosapogenol.

Tetrahedron Letters, 365 (1967)
By T. Nakano, M. Hasegawa, T. Fukumaru, S. Tobinaga, C. Djerassi, L. J. Durham and H. Budzikiewicz.

584.     Optical Rotatory Dispersion Studies CVII. Factors Governing the Relative Stability of Hydrindanones. Syntheses of 17-Alkyl-15-keto Steroids.

J. Am. Chem. Soc., 89, 651 (1967)
By A. R. Van Horn and C. Djerassi.

585.     Mass Spectrometry in Structural and Stereochemical Problems CXXIX. The Course of the Electron Impact‑induced Elimination of Hydrogen Sulphide from Aliphatic Thiols.

Chem. Comm., 109 (1967)
By A. M. Duffield, W. Carpenter and C. Djerassi,

586.     Mass Spectrometry in Structural and Stereochemical Problems CXXVIII. Further Studies on the Mass Spectrometry of 15-Keto Steroids.

Steroids, 9, 163 (1967)
By A. R. Van Horn and C. Djerassi.

587.     Deuterium Isotope Effect in the Photochemistry of a 20-0xo-Steroid Analog

Chem. and Ind., 358 (1967)
By C. Djerassi and B. Zeeh.

588.     Mass Spectrometry in Structural and Stereochemical Problems. CXXIV. Mass Spectral Fragmentation of Alkylquinolines and Isoquinolines.

J. Org. Chem., 32, 997 (1967)
By Shelia D. Sample, D. A. Lightner, O. Buchardt and C. Djerassi.

589.     Mass Spectrometry in Structural and Stereochemical Problems CXXV. Mass Spectrometry of Some Steroid Trimethylsilyl Ethers.

J. Org. Chem., 32, 1005 (1967)
By John Diekman and C. Djerassi.

590.     Mass Spectrometry in Structural and Stereochemical Problems CXXVI. Synthesis and Fragmentation Behavior of Deuterium-Labeled 17-Keto Steroids.

J. Org. Chem., 32, 1012 (1967)
By L. Tökes, R. T. LaLonde and C. Djerassi.

591.     Mass Spectrometry in Structural and Stereochemical Problems CXXVII. Synthesis and Fragmentation Be­havior of Deuterium-Labeled 20-Keto Steroids.

J. Org. Chem., 32, 1020 (1967)
By L. Tökes, R. T. LaLonde and C. Djerassi.

592.     Mass Spectrometry in Structural and Stereochemical Problems CXXII. Possible Operation of Tautomerism Before and After Electron-Impact Induced Fragmentation of Molecular Ions.

Tetrahedron, 23, 2095 (1967)
By J. K. MacLeod, J. B. Thomson and C. Djerassi,

593.     Optical Rotatory Dispersion Studies CX. On the Stereo-chemistry of Some Optically Active Cyclobutanones.

Bull. Soc. Chim. France, 950 (1967)
By J. Gore, C. Djerassi and J.-M. Conia.

 

 

 

594.     Mass Spectrometry in Structural and Stereochemical Problems CXXX. A Study of Electron Impact Induced Migratory Aptitudes.

J. Am. Chem. Soc., 89, 2711 (1967)
By P. Brown and C. Djerassi.

595.     Mass Spectrometry in Structural and Stereochemical Problems CXXXIII. Electron Impact Induced Rearrange­ment Reactions of Organic Molecules.

Angew. Chem. Intern. Ed. Eng., 6, 477 (1967)
By P. Brown and C. Djerassi.

595a. Elektronenstoss-induzierte Umlagerungen organischer Moleküle.

Angew. Chem., 79, 481 (1967)
By P. Brown and C. Djerassi.

596.     Mass Spectrometry in Structural and Stereochemical Problems CXXXI. The Mass Spectrometric Fragmentation of Thiuramdisulfides.

J. Org. Chem., 32, 2054 (1967)
By J. 0. Madsen, Sven-Olov Lawesson, A. M. Duffield and C. Djerassi.

597.     Electron Impact Induced Fragmentation of Organic Molecules

Proc. Symp. "Some Newer Physical Methods in Structural Chemistry, Mass Spectrometry, Optical Rotatory Dispersion and Circular Dichroism," United Trade Press, London (1967), pp. 2-6.
By C. Djerassi.

598.     Some Applications of Newer Physical Methods in the Steroid Field.

Proc. Second Internat. Congress Hormonal Steroids, Excerpta Medica Foundation, Amsterdam, 1967, pp. 3-15
By C. Djerassi.

599.     Methods for Selective Deuteration of Nuclear Positions in the Steroid Field.

Proc. Second Internat. Congress Hormonal Steroids, Excerpta Medica Foundation, Amsterdam, 1967, pp. 261-268
By C. Djerassi.

600.     Mass Spectrometry in Structural and Stereochemical Problems CXVII. Aliphatic α,β-Epoxyketones.

Tetrahedron, 23, 2893 (1967)
By W. Reusch and C. Djerassi.

601.     The Photolysis of 1-Phenyl and 1-Cyano Substituted Iso­quinoline Iso-quinoline N-oxides to Benz[f]-1,3-Oxazepines.

Tetrahedron Letters, 2741 (1967)
By O. Buchardt, C. Lohse, A. M. Duffield and C. Djerassi.

602.     Mass Spectrometry in Structural and Stereochemical ­Problems. CXXXII. Electron Impact Induced Alkyl and Aryl Rearrangements in α,β-Unsaturated Cyclic Ketones.

J. Am. Chem. Soc., 89, 4765 (1967)
By R. L. N. Harris, F. Komitsky, Jr. and C. Djerassi.

603.     Mass Spectrometry in Structural and Stereochemical Problems. CXXXIV. Electron Impact Induced Alkyl and Aryl Rearrangements in α-Arylidene Cyclic Ketones.

J. Am. Chem. Soc., 89, 4775 (1967)
By R. L. N. Harris, F. Komitsky, Jr., and C. Djerassi.

604.     Macrolide Antibiotics XV. Nystatin - The Structure of the Aglycone.

Tetrahedron Letters, 3745 (1567)
By M. Ikeda, M. Suzuki and C. Djerassi.

605.     Mass Spectrometry in Structural and Stereochemical Problems. CXXXVI. Primary Hydrogen Isotope Effects in the McLafferty Rearrangement.

J. Am. Chem. Soc., 89, 5182 (1967)
By J. K. MacLeod and C. Djerassi.

606.     Mass Spectrometry in Structural and Stereochemical Problems. CXXXVII. Examples of Interaction of Remote Functional Groups after Electron Impact.

J. Am. Chem. Soc., 89, 5190 (1967)
By M. M. Green and C. Djerassi.

607.     Terpenoids LX. The Structures of the Cactus Triterpene Lactones Stellatogenin and Thurberogenin.

J. Org. Chem., 32, 3150 (1967)
By M. Marx, J. Leclercq, B. Tursch and C. Djerassi.

608.     Alkaloids of Callichilia subsessilis. Cailichiline.

Bull. Soc. Chin. France, 2669 (1967)
By M. Plat, N. Kunesch, J. Poisson, C. Djerassi and H. Budzikiewicz.

609.     Mass Spectrometry in Structural and Stereochemical Problems. CXXXV. Fragmentation and Synthesis of α-Hydrindanones and Deuterated Analogs.

Chem. Ber., 100, 3204 (1967)
By B. Zeeh, G. Jones and C. Djerassi.

610.     Mass Spectrometry in Structural and Stereochemical Problems. CXLVII. The Course of the Electron Impact Induced Elimination of Hydrogen Fluoride in Primary Alkyl Fluorides.

Chem. Comm., 1022 (1567)
By W. Carpenter, A. M. Duffield and C. Djerassi.

611.     Mass Spectrometry in Structural and Stereochemical Problems. CXL. Competitive McLafferty Rearrangements in Bifunctional Compounds.

J. Org. Chem., 32, 3485 (1967)
By J. K. MacLeod and C. Djerassi.

612.     Mass Spectrometry in Structural and Stereochemical Problems. CXLIII. Unusual Fragmentations in the Mass Spectra of Some Aliphatic Ethers.

J. Am. Chem. Soc., 89, 6164 (1967)
By W. Carpenter, A. M. Duffield and C. Djerassi.

 

613.     Mass Spectrometry in Structural and Stereochemical Problems. CXLV. Factors Governing the Preferential Loss of Small versus Large Radicals in Ketones, Schiff Bases and Ethers.

J. Am. Chem. Soc., 89, 6167 (1967)
By W. Carpenter, A. M. Duffield and C. Djerassi.

614.     Magnetic Circular Dichroism Studies. III. Investigation of Some Optically Active Chlorins.

J. Am. Chem. Soc., 89, 6170 (1967)
By B. Briat, D. A. Schooley, R. Records, E. Bunnenberg and C. Djerassi.

615.     Alkaloid Studies. LVIII. The Alkaloids of Six Aspidosperma Species.

Phytochemistry, 6, 1653 (1967)
By R. R. Arndt, S. H. Brown, N. C. Ling, P. Roller, C. Djerassi, J. M. Ferreira F., B. Gilbert, E. C. Miranda and S. E. Flores.

616.     Mass Spectrometry in Structural and Stereochemical Problems. CXLI. Electron Impact Induced Fragmentations and Rearrangements of Trimethylsilyl Ethers, Amines, and Sulfides.

J. Org. Chem., 32, 3904 (1967)
By J. Diekman, J. G. Thomson and C. Djerassi.

617.     Mass Spectrometry in Structural and Stereochemical Problems. CLI. Further Studies on the Mass Spectrometry of 17-Keto Steroids.

Steroids, 10, 653 (1967)
By G. Jones and C. Djerassi.

618.     Magnetic Circular Dichroism Studies. IV. Investigation of Some Annulene Derivatives.

J. Am. Chem. Soc., 89, 7062 (1967)
By B. Briat, D. A. Schooley, R. Records, E. Bunnenberg and C. Djerassi.

619.     Mass Spectrometry in Structural and Stereochemical Problems. CXXXVIII. Fragmentation Processes of Some Thiocarbonyl Compounds on Electron Impact.

Acta Chem. Scand., 21, 2167 (1967)
By A. M. Duffield, C. Djerassi and J. Sandström

620.     A High Priority? Research Centers in Developing Nations.

Bulletin of the Atomic Scientists, Jan. 1968, pp. 23-27
By C. Djerassi.

621.     Mass Spectrometry in Structural and Stereochemical Problems. CXLIV. Unusual Fragmentations of the Low-Voltage Spectra of Aliphatic Ketones.

J. Am. Chem. Soc., 90, 160 (1968)
By W. Carpenter, A. M. Duffield and C. Djerassi.

 

 

 

 

622.     Mass Spectrometry in Structural and Stereochemical Problems. CXLVI. Mass Spectrometric Fragmentations Typical of Sterols with Unsaturated Side Chains.

J. Org. Chem., 33, 305 (1968)
By S. G. Wyllie and C. Djerassi.

623.     Mass Spectrometry in Structural and Stereochemical Problems. CXLIX. The Question of Ring Expansion in the Fragmentation of 13C-Labeled Nitrogen Heterocycles.

J. Am. Chem. Soc., 90, 678 (1968)
By M. Marx and C. Djerassi.

624.     Homogeneous Catalytic Hydrogenation and Deuteration of Steroids.

Chem. Ber., 101, 58 (1968)
By W. Voelter and C. Djerassi.

625.     Terpenoids LXI. The Structure of a New Triterpene, Putranjivadione.

Tetrahedron, 24, 1205 (1968)
By P. Sengupta, A. K. Chakraborty, A. M. Duffield, L. J. Durham and C. Djerassi.

626.     Optical Rotatory Dispersion Studies CXI. The Octant Rule and Equatorial Alkoxycarbonyl and Carboxyl Groups. Synthesis of Optically Active Adamantanones.

Tetrahedron Letters, 1097 (1968)
By W. S. Briggs, M. Suchy And C. Djerassi.

627.     Mass Spectrometry in Structural and Stereochemical Problems. CXXXIX. The Fragmentation of Some Cyanohydrins and O-Acylcyanohydrins Upon Electron Impact.

Arkiv Kemi, 28, 435 (1968)
By G. Schroll, S.-O. Lawesson, A. M. Duffield and C. Djerassi.

628.     Mass Spectrometry in Structural and Stereochemical Problems. CLIII. Electron Impact Promoted Frag­mentation of N-Alkyl Cyanides.

Org. Mass Spectr., 1, 3 (1968)
By W. Carpenter, Y. M. Sheikh, A. M. Duffield and C. Djerassi.

629.     Mass Spectrometry in Structural and Stereochemical Problems. CL. Fragmentation and Synthesis of Bicyclic and Monocyclic Models of 20-Keto Steroids.

Chem. Ber., 101, 1018 (1968)
By B. Zeeh, G. Jones and C. Djerassi.

630.     Some Applications of Magnetic Circular Dichroism and Optical Rotatory Dispersion.

Nature, 217, 918 (1968)
By B. Briat and C. Djerassi.

 

631.     Mass Spectrometry in Structural and Stereochemical Problems. CXXIII. Mass Spectrometry of Depsides, Depsidones, Dibenzofurans, and Diphenylbutadienes with Positive and Negative Ions.

Tetrahedron, 24, 2707 (1968)
By S. Huneck, C. Djerassi, D. Becher, M. Barber, Von Ardenne, K. Steinfelder and R. Tümmler.

632.     Mass Spectrometry in Structural and Stereochemical Problems. CXLII. Electron Impact Induced Analogies to Thermal Elimination Processes in S-Methyl Xan­thates and Esters.

J. Org. Chem., 33, 1612 (1968)
By W. Scott Briggs and C. Djerassi.

633.     The Pyrolysis of the Epimeric d0- and 2-d1-2- Methylcyclohexyl-S-Methyl Xanthates and Acetates.

J. Org. Chem., 33, 1625 (1968)
By W. Scott Briggs and C. Djerassi.

634.     Mass Spectrometry in Structural and Stereochemical Problems. CLIX. The Question of Ring Expansion in the Electron Impact-induced Fragmentation of Aromatic Amines.

Chem. Comm., 414 (1968)
By A. V. Robertson, M. Marx and C. Djerassi.

635.     Mass Spectrometry in Structural and Stereochemical Problems. CLII. Electron Impact Promoted Frag­mentation of Some Substituted Germacyclopentanes and Germacyclopentenes.

J. Organometallic Chem., 12, 123 (1968)
By A. M. Duffield, C. Djerassi, P. Mazerolles, J. Dubac and G. Manuel.

636.     Alkaloid Studies. LIX. The Structure and Absolute Configuration of Vallesamidine.

J. Am. Chem. Soc., 90, 2445 (1968)
By S. H. Brown, C. Djerassi and P. G. Simpson.

637.     Mass Spectrometry in Structural and Stereochemical Problems. CXLVIII. Electron Impact Induced Fragmentations of Cyclic Sulfites and Carbonates.

Tetrahedron, 24, 2949 (1968)
By P. Brown and C. Djerassi.

638.     Selective Ketalization of Steroid Ketones with Tris-triphenylphosphin-rhodium Chloride.

Chem. Ber., 101, 1154 (1968)
By W. Voelter and C. Djerassi.

639.     Terpenoids LXII. Eunicellin, a Diterpenoid of the Gorgonian Eunicella Stricta. X-Ray Diffraction Analysis of Eunicellin Dibromide.

Tetrahedron Letters, 2879 (1968)
By O. Kennard, D. G. Watson, L. Riva di Sanseverino, B. Tursch, R. Bosmans and C. Djerassi.

640.     Mass Spectrometry in Structural and Stereochemical Problems. CLIV. Electron Impact Promoted Frag­mentation of Alkyl Tetrahydropyranyl Ethers and Thioethers.

J. Org. Chem., 33, 2266 (1968)
By S. J. Isser, A. M. Duffield and C. Djerassi.

641.     Mass Spectrometry in Structural and Stereochemical Problems. CLV. The Electron Impact Induced Frag­mentations and Rearrangements of Some Trimethyl­silyl Ethers of Aliphatic Glycols and Related Compounds.

J. Org. Chem., 33, 2271 (1968)
By J. Diekman, J. B. Thomson and C. Djerassi.

642.     Mass Spectrometry in Structural and Stereochemical Problems. CLXIII. Rearrangement Reactions in Organic Mass Spectrometry.

Advances in Mass Spectrometry, C. E. Kendrick, ed. The Institute of Petroleum, London, 1968, Vol. 4, pp. 199-210
By C. Djerassi.

643.     Mass Spectrometry in Structural and Stereochemical Problems. CLVIII. Electron Impact Promoted Fragmentation of Triphenylmethyl Ethers.

Org. Mass Spectr., 1, 251 (1968)
By Y. M. Sheikh, A. M. Duffield and C. Djerassi.

644.     Mass Spectrometry in Structural and Stereochemical Problems. CLX. On the Supposed Peri Interaction in 4-Isobutylquinoline.

J. Org. Chem., 33, 2962 (1968)
By T. Muraski and C. Djerassi.

645.     Magnetic Circular Dichroism Studies V. Investigation of Some Cyclopentaene Derivatives.

J. Am. Chem. Soc., 90, 4691 (1968)
By B. Briat, D. A. Schooley, R. Records, E. Bunnenberg, C. Djerassi and E. Vogel.

646.     Mass Spectrometry in Structural and Stereochemical Problems. CLXI. Elucidation of the Course of the Characteristic Ring D Fragmentation of Steroids.

J. Am. Chem. Soc., 90, 5465 (1968)
By L. Tökés, G. Jones and C. Djerassi.

647.     Magnetic Circular Dichroism Studies VI. Investigation of Some Purines, Pyrimidines and Nucleosides.

J. Am. Chem. Soc., 90, 6163 (1968)
By W. Voelter, R. Records, E. Bunnenberg and C. Djerassi.

648.     Mass Spectrometry in Structural and Stereochemical Problems. CLVI. 1,4-Dihydropyridines Preparation and Spectroscopic Properties.

Arkiv Kemi, 29, 525 (1968)
By G. Schroll, S. P. Nygaard, S.-O. Lawesson, A. M. Duffield and C. Djerassi.

649.     Mass Spectrometry in Structural and Stereochemical Problems. CLXIV. Electron Impact Promoted Frag­mentation of Some Thiosemicarbazones.

Org. Mass Spectr., 1, 633 (1968)
By M. Younus Sheikh, A. M. Duffield and C. Djerassi.

650.     Alkaloid Studies LX. The Structures of Two Novel Aspidosperma Alkaloids, Deoxyaspidodispermine and Aspidodispermine.

Tetrahedron Letters, 5837 (1968)
By M. Ikeda and C. Djerassi.

651.     Mass Spectrometry in Structural and Stereochemical Problems. CLXV. A Study of Skeletal Rearrangements in     13C-Labeled Aromatic Amines.

J. Am. Chem. Soc., 90, 6992 (1968)
By A. V. Robertson and C. Djerassi.

652.     Mass Spectrometry in Structural and Stereochemical Problems. CLXVII. Long Range Hydrogen Transfers in Mass Spectrometry.

Helv. Chim. Acta, 51, 1750 (1968)
By R. Brandt and C. Djerassi.

653.     Mass Spectrometry in Structural and Stereochemical Problems. CLVII. A Study of the Fragmentation Processes of Some N-Acyl-2-Indolinols Upon Electron Impact.

Acta. Chem. Scand., 22, 2329 (1968)
By O. Buchardt, A. M. Duffieldand C. Djerassi.

654.     Optical Rotatory Dispersion Studies CXII. An Octant Rule for the Thiocyanate Chromophore and its Application to Rotameric Equilibrium Studies in the Steroid Series.

Tetrahedron, 24, 6913 (1968)
By C. Djerassi, D. A. Lightner, D. A. Schooley, K. Takeda, T. Komeno and K. Kuriyama.

655.     Optical Rotatory Dispersion Studies CXIII. Molybdate-­Pyranose Complexes.

Ann., 718, 238 (1968)
By W. Voelter, E. Beyer, R. Records, E. Bunnenberg and C. Djerassi.

656.     Mass Spectrometry in Structural and Stereochemical Problems. CLXVI. The Electron Impact Promoted Fragmentation of Some Aliphatic 1,2-Glycols.

Org. Mass Spectr., 1, 777 (1968)
By J. Kossanyi, J. P. Morizur, B. Furth, J. Wiemann, A. M. Duffield and C. Djerassi.

657.     Alkaloid Studies LXI. The Structure of Twelve New Alkaloids from Aspidosperma Cylindrocarpon.

Journal Chem. Soc. (C), 417 (1969)
By B. V. Milborrow and C. Djerassi.

658.     Magnetic Circular Dichroism Studies VII, Some Derivatives of Vitamin B12.

Bull. Soc. Chim. France, 135 (1969)
By B. Briat and C. Djerassi.

659.     Optical Rotatory Dispersion Studies CXIV. Molybdate-­Polyalkohol-Complexes.

Chem. Ber., 102, 1005 (1969)
By W. Voelter, E. Bayer, R. Records, E. Bunnenberg and C. Djerassi.

660.     Mass Spectrometry in Structural and Stereochemical Problems CLXVIII. Effect of Fluorine Substitution on the McLafferty Rearrangement of Aliphatic Ketones.

Org. Mass Spectr., 2, 317 (1969)
By W. Carpenter, A. M. Duffield and C. Djerassi.

661.     Mass Spectrometry in Structural and Stereochemical Problems CLXIX. Determination of the Structures of the Ions in the Single and Double McLafferty Rearrangements by Ion Cyclotron Resonance Spectroscopy.

J. Am, Chem. Soc., 91, 2069 (1969)
By J. Diekman, J. K. MacLeod, C. Djerassi and J. D. Baldeschwieler.

662.     Optical Rotatory Dispersion Studies CXVI, The Circular Dichroism of Some Lactic Acid Derivatives. A Reinterpretation.

Chem. Comm., 355 (1969)
By G. Barth, W. Voelter, E. Bunnenberg and C. Djerassi.

663.     Mass Spectrometry in Structural and Stereochemical Problems CLXX. A Study of the Effect of Ring Size in Reciprocal Hydrogen Transfer.

J. Am. Chem. Soc., 91, 2724 (1969)
By G. Eadon and C. Djerassi.

664.     Applications of Artificial Intelligence for Chemical Inference I. The Number of Possible Organic Compounds. Acyclic Structures Containing C, H, O and N.

J. Am. Chem. Soc., 91, 2973 (1969)
By J. Lederberg, G. L. Sutherland, B. G. Buchanan, E. A. Feigenbaum, A. V. Robertson, A. M. Duffield, and C. Djerassi.

665.     Applications of Artificial Intelligence for Chemical Inference II.  Interpretation of Low Resolution Mass Spectra of Ketones.

J. Am. Chem. Soc., 91, 2977 (1969)
By A. M. Duffield, A. V. Robertson, C. Djerassi, B. G. Buchanan, G. L. Sutherland, E. A. Feigenbaum and J. Lederberg.

666.     Mass Spectrometry in Structural and Stereochemical Problems CLXII. A Study of the Fragmentation Processes of Some Benzoxazepines upon Electron Impact.

Acta. Chem. Scand., 23, 126 (1969)
By O. Buchardt, A. M. Duffield and C. Djerassi.

667.     Optical Rotatory Dispersion Studies CXV. α-Hydroxy Acid—Molybdate Complexes.

Chem. Ber., 102, 2003 (1969)
By W. Voelter, E. Beyer, G. Barth, E. Bunnenberg and C. Djerassi.

 

668.     Mass Spectrometry in Structural and Stereochemical Problems CLXXI. Factors Governing the Loss of Small vs. Large Radicals in the α-Fission of Aliphatic Amines.

Org. Mass Spectr., 2, 625 (1969)
By C. A. Brown, A. M. Duffield and C. Djerassi.

669.     Mass Spectrometry in Structural and Stereochemical Problems CLXXII. The Electron Impact Promoted Fragmentation of 1,2-Cyclohexanedioi.

Org. Mass Spectr., 2, 631 (1969)
By M. K. Strong and C. Djerassi.

670.     Mass Spectrometry in Structural and Stereochemical Problems CLXXIV. Electron Impact Induced Fragmenta­tion of Some Aryl- and Alkylsulfonylthioureas.

Org. Mass Spectr., 2, 641 (1969)
By A. M. Duffield, C. Djerassi, R. Neidlein, and E. Heukelbach.

671.     Mass Spectrometry in Structural and Stereochemical Problems CLXXVII. Application of Ion Cyclotron Resonance to the Structure Elucidation of the C3H6O Ion Formed in the Double McLafferty Rearrangement.

J. Am. Chem. Soc., 91, 3986 (1969)
By G. Eadon, J. Diekman and C. Djerassi.

672.     Terpenoids LXIV. Chemical Studies of Marine Inverte­brates V. The Isolation of Three New Holothurinogenins and Their Chemical Correlation with Lanosterol.

J, Am. Chem. Soc., 91, 4918 (1969)
By P. Roller, C. Djerassi, R. Cloetens and B. Tursch,

673.     Mass Spectrometry in Structural and Stereochemical Problems CLXXVI. The Course of the Electron Impact Induced Fragmentation of Androstane.

J. Am. Chem. Soc., 91, 5017 (1969)
By L. Tökés and C. Djerassi.

674.     Terpenoids LXIII. The Structure of Jegosapogenol and the Configuration at C-21 and C-22 in Barringtogenol D, Aescigenin, Protoaescigenin and Isoaescigenin.

J. Org. Chem., 34, 3135 (1969)
By T. Nakano, M. Hasegawa, T. Fukumaru, L. J. Durham, H. Budzikiewicz and C. Djerassi.

675.     Mass Spectrometry in Structural and Stereochemical Problems CLXXIII. The Electron Impact induced Frag­mentations and Rearrangements of Trimethylsilyl Esters of ω-Phenoxyalkanoic Acids.

J. Org. Chem., 34, 3147 (1969)
By J. Diekman, J. B. Thomson and C. Dierassi.

676.     Prognosis for the Development of New Chemical Birth Control Agents.

Science, 166, 468 (1969)
By Carl Djerassi.

677.     Magnetic Circular Dichroism Studies VIII. Investigation of Some Purine Cyclonucleosides.

J. Am. Chem. Soc., 91, 6165 (1969)
By W, Voelter, G. Barth, R. Records, E. Bunnenberg and C. Djerassi.

678.     Magnetic Circular Dichroism Studies IX.  The Magnetic Circular Dichroism of Carbonyl Compounds.

Chem. Comm., 1246 (1969)
By G. Barth, E. Bunnenberg and C. Djerassi.

679.     Mass Spectrometry in Structural and Stereochemical Problems CLXXIX. The Electron Impact Induced Rearrangement of 1-Phenylheptenes. Further Evidence for Double Bond Lability.

J. Am. Chem. Soc., 91, 6808 (1969)
By A. F. Gerrard and C. Djerassi.

680.     Mass Spectrometry in Structural and Stereochemical Problems CLXXXIII. A Study of the Electron Impact Induced Fragmentation of Aliphatic Aldehydes.

J. Am. Chem. Soc., 91, 6814 (1969)
By R. J. Liedtke and C. Djerassi.

681.     Mass Spectrometry in Structural and Stereochemical Problems CLXXXVI. Electron Impact Promoted Eight-Membered Hydrogen Transfer in Vinyl Ethers.

Chem. Comm., 1385 (1969)
By M. Katoh and C. Djerassi.

682.     Mass Spectrometry in Structural and Stereochemical Problems CLXXX. Oxygen Rearrangement and Fragmentation Reactions After Electron Impact on 4-Hydroxy- and 4-Alkoxy-1-Decalones.

J. Org. Chem., 34, 4091 (1969)
By R. T. Gray, M. Ikeda and C. Djerassi.

683.     Applications of Artificial Intelligence for Chemical Inference III. Aliphatic Ethers Diagnosed by Their Low Resolution Mass Spectra and NMR Data.

J. Am. Chem. Soc., 91, 7440 (1969)
By G. Schroll, A. M. Duffield, C. Djerassi, B. G. Buchanan, G. L. Sutherland, E. A. Feigenbaum and J. Lederberg.

684.     Mass Spectrometry in Structural and Stereochemical Problems CLXXVIII. The Electron Impact Promoted Fragmentation of 1,2-Cyclohexane Oxide.

Org. Mass Spectr., 2, 1201 (1969)
By M. K. Strong, P. Brown and C. Djerassi.

685.     Mass Spectrometry in Structural and Stereochemical Problems CLXXV. The Mass Spectra of α-Hydroxy Ketones. Evidence Against Electron Impact Induced Alkyl Shifts in Ketols.

Journal Chem. Soc.(C), 2550 (1969)
By C. A. Brown and C. Djerassi.

 

686.     Alkaloid Studies LXII. X-ray Crystallographic Structure Determination of Dichotine Hydrobromide.

J. Am. Chem. Soc., 92, 222 (1970)
By N. C. Ling, C. Djerassi and P. G. Simpson

687.     Mass Spectrometry in Structural and Stereochemical Problems CXC. Electron Impact Induced Triple Hydrogen Migration in Vinyl Alkyl Ethers.

J. Am. Chem. Soc., 92, 731 (1970)
By M. Katoh and C. Djerassi.

688.     Optical Rotatory Dispersion Studies CXVII. Absolute Configurational Assignments of Some α-Substituted Phenyl‑acetic Acids by Circular Dichroism Measurements.

J. Am. Chem. Soc., 92, 875 (1970)
By G. Barth, W. Voelter, H. S. Mosher, E. Bunnenberg and C. Djerassi.

689.     Terpenoids LXV. Chemical Studies of Marine Invertebrates. Praslinogenin, a New Holothurinogenin from the Indian Ocean Sea Cucumber, Bohadschia koellikeri.

Tetrahedron Letters 467 (1970)
By B. Tursch, R. Cloetens and C. Djerassi.

690.     Mass Spectrometry in Structural and Stereochemical Problems CLXXXII. Investigations in the 10-Phenyl-2-Decalone System. The Synthesis and Electron-Impact Promoted Phenyl Migration of trans-10-Phenyl-2-Octalone.

J. Org. Chem., 35, 753 (1970)
By R. T. Gray and C. Djerassi.

691.     Magnetic Circular Dichroism Studies XI. Investigation of Some Adenosine Cyclonucleosides.

Tetrahedron Letters, 727 (1970)
By D. L. Elder, E. Bunnenberg, C. Djerassi, M. Ikehara and W. Voelter.

692.     Demonstration of a Biogenetically Unprecedented Side Chain in the Marine Sterol, Gorgosterol.

J. Am. Chem. Soc., 92, 2179 (1970)
By R. L. Hale, J. Leclercq, B. Tursch, C. Djerassi R. A. Gross, Jr., A. J. Weinheimer, K. Gupta, and Paul J. Scheuer.

693.     Mass Spectrometry in Structural and Stereochemical Problems CLXXXIV. Charge Localization in Fragment Ions of Amino Ketones and Esters.

Org. Mass Spectr., 3, 439 (1970)
By J. Cable, G. W. Adelstein, J. Gore and C. Djerassi.

694.     Mass Spectrometry in Structural and Stereochemical Problems CLXXXV. Effect of the Phenyl Group in the Moss Spectra of Trans-10-Phenyl-2-Decalone and Trans-­10-Phenyldecalin.

Org. Mass Spectr., 3, 245 (1970)
By R. T. Gray and C. Djerassi.

 

695.     Mass Spectrometry in Structural and Stereochemical Problems CLXXXI. Further Studies of Remote Group Interactions After Electron Impact in 4-Substituted Cyclohexanones.

J. Org. Chem.,      35, 1525 (1970)
By R. T. Gray, R. J. Spangler, and C. Djerassi.